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  1. 060 工学部
  2. 0601 学術論文

Photocatalytic degradation of chlorinated propenes using TiO2

http://hdl.handle.net/10091/00018774
2bd4797d-7d49-49e4-b0b8-4d959129b603
名前 / ファイル ライセンス アクション
Photocatalytic_degradation_chlorinated_propenes.pdf Photocatalytic_degradation_chlorinated_propenes.pdf (3.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-04-21
タイトル
言語 en
タイトル Photocatalytic degradation of chlorinated propenes using TiO2
言語
言語 eng
キーワード
主題Scheme Other
主題 Titanium dioxide
キーワード
主題Scheme Other
主題 Photocatalysis
キーワード
主題Scheme Other
主題 Chlorinated propene
キーワード
主題Scheme Other
主題 Chlorinated butene
キーワード
主題Scheme Other
主題 Degradation
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Nishikiori, Hiromasa

× Nishikiori, Hiromasa

WEKO 50330

Nishikiori, Hiromasa

Search repository
Sato, Yohei

× Sato, Yohei

WEKO 50331

Sato, Yohei

Search repository
Oki, Kyoichi

× Oki, Kyoichi

WEKO 50332

Oki, Kyoichi

Search repository
Fujii, Tsuneo

× Fujii, Tsuneo

WEKO 50333

Fujii, Tsuneo

Search repository
信州大学研究者総覧へのリンク
氏名 Nishikiori, Hiromasa
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html
出版者
出版者 SPRINGER
引用
内容記述タイプ Other
内容記述 RESEARCH ON CHEMICAL INTERMEDIATES. 41(10):7641-7654 (2015)
書誌情報 RESEARCH ON CHEMICAL INTERMEDIATES

巻 41, 号 10, p. 7641-7654, 発行日 2015-10
抄録
内容記述タイプ Abstract
内容記述 The photocatalytic degradation of chlorinated propenes using TiO2 was investigated by FTIR spectroscopy. The chlorinated propenes were degraded to HCl, CO2, CO, H2O, and HCOOH during UV irradiation. During the degradation of 3-chloro-1-propene, the concentrations of CO2, CO, and HCOOH increased just after starting the irradiation. The onset of the HCl formation was delayed. On the other hand, the onset of the HCOOH formation was delayed during the degradation of 1-chloro-1-propene. During the degradation of 2-chloro-1-propene, the rate of the HCOOH production was slower than that during the degradation of 3-chloro-1-propene although the HCl production was not delayed. These results indicated that HCOOH was produced by the degradation of the double-bonded carbon bonding to two H atoms during the initial stage. The chlorinated compounds were preferentially produced from the double-bonded carbon bonding to the Cl atom and rapidly degraded to HCl, CO2, and CO during the initial stage. The residual part was degraded in the latter steps. Furthermore, it is suggested that the Cl atom on one of the double-bonded C atoms of the propenes was transferred to the other C atom before the degradation. Consequently, the double-bonded carbon bonding to two H atoms in 2-chloro-1-propene was chlorinated, then degraded to HCl, CO2, and CO during the initial stage.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0922-6168
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10679655
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1007/s11164-014-1849-5
関連名称
関連名称 10.1007/s11164-014-1849-5
権利
権利情報 The final publication is available at www.springerlink.com
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000361481800051
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