{"created":"2021-03-01T06:22:17.402387+00:00","id":19210,"links":{},"metadata":{"_buckets":{"deposit":"4bfce278-587f-411b-af44-b25f4cc5340f"},"_deposit":{"id":"19210","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19210"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019210","sets":["1309:1310"]},"author_link":["104227","104228","104229"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"832","bibliographicPageStart":"822","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have synthesized two novel phthalocyanines, (m-SF5PhO)(8)PcCu (7b) and (p-SF5PhO)(8)PcCu (7c), in order to investigate their flying-seed-like mesomorphism. Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the derivative (m-SF5PhO)(8)PcCu (7b) substituted a SF 5 group at m-position showed a Col(10)(P2(1)/a) (= p2gg) mesophase from rt to 315.0 degrees C, whereas the derivative (p-SF5PhO)(8)PcCu (7c) substituted a SF 5 group at p-position showed a crystalline (K) phase from rt to the decomposition temperature at ca. 336 degrees C without showing mesomorphism. Thus, the novel phthalocyanine derivative (m-SF5PhO)(8)PcCu (7b) substituted a strong electron withdrawing SF 5 group at m-position shows only one columnar mesophase in a very wide temperature region from rt to 315.0 degrees C. Furthermore, the Q-band wavelengths (672.2 and 672.1 nm) of the present (m-SF5PhO)(8)PcCu (7b) and (p-SF5PhO)(8)PcCu (7c) are shorter than that (680.3 nm) of the previous [(m-C-1) PhO](8)PcCu (5c) derivative. It can be attributed to strong electron withdrawing nature of the SF5 group on the phenoxy group.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 20(7):822-832 (2016)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Ohta, Kazuchika","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000387058600008"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WORLD SCI PUBL CO INC"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1142/S1088424616501005"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1142/S1088424616501005","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 20, Issues: 7(2016) pp. 822-832, DOI: 10.1142/S1088424616501005 © 2016 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1088-4246","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11202421","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Watarai, Ayumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta, Kazuchika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yasutake, Mikio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-09-26"}],"displaytype":"detail","filename":"Flying-seed-like_mesogens_6.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensefree":"Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 20, Issues: 7(2016) pp. 822-832, DOI: 10.1142/S1088424616501005 © 2016 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Flying-seed-like_mesogens_6.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19210/files/Flying-seed-like_mesogens_6.pdf"},"version_id":"285a2ee8-3bb9-4abc-b70b-c5703ab0cbef"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"flying-seed-like liquid crystals","subitem_subject_scheme":"Other"},{"subitem_subject":"metallomesogen","subitem_subject_scheme":"Other"},{"subitem_subject":"phthalocyanine","subitem_subject_scheme":"Other"},{"subitem_subject":"columnar mesophase","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Flying-seed-like mesogens 6: Synthesis and mesomorphism of phthalocyanine derivatives substituted by pentafluorosulfanylphenoxy group","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Flying-seed-like mesogens 6: Synthesis and mesomorphism of phthalocyanine derivatives substituted by pentafluorosulfanylphenoxy group","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-09-26"},"publish_date":"2017-09-26","publish_status":"0","recid":"19210","relation_version_is_last":true,"title":["Flying-seed-like mesogens 6: Synthesis and mesomorphism of phthalocyanine derivatives substituted by pentafluorosulfanylphenoxy group"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:14:51.287891+00:00"}