{"created":"2021-03-01T06:22:17.526305+00:00","id":19212,"links":{},"metadata":{"_buckets":{"deposit":"cb223ad2-3b71-4bc8-b111-4c91a0b14438"},"_deposit":{"id":"19212","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19212"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019212","sets":["1309:1310"]},"author_link":["104233","104234","104235"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"58","bibliographicPageStart":"48","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF PORPHYRINS AND PHTHALOCYANINES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have synthesized three novel octakis(m-chloropyridyloxy) phthalocyaninato copper(II) complexes, [x-PyO(m-Cl)](8)PcCu(x = 2, 3, 4: 2a-2c), keeping a chlorine atom at the meta position on the 2-, 3- and 4-pyridyloxy group, in which the nitrogen atom is located at the 2-, 3-and 4-positions, respectively. Their phase transition behavior and the mesophase structure have been established by using a polarizing optical microscope, a differential scanning calorimeter, and a temperature-dependent small angle X-ray diffractometer. Very interestingly, the mesomorphism appears with strong dependence of the position of nitrogen in m-chloropyridyloxy group. The derivative [3-PyO(m-Cl)](8)PcCu (2b) introduced a nitrogen atom at the 3-position is not mesogenic but crystalline. On the other hand, the derivative [2-PyO(m-Cl)](8)PcCu (2a) introduced a nitrogen atom at the 2-position shows columnar mesomorphism only at very high temperatures over 325 degrees C. The derivative [4-PyO(m-Cl)](8)PcCu (2c) introduced a nitrogen atom at the 4-position shows columnar mesomorphism in a very wide temperature region from rt to the decomposition temperature at 306 degrees C. From the viewpoint of N center dot center dot center dot Cl halogen bond, we have discussed about relationship between their mesomorphism and the position of nitrogen atom in m-chloropyridyloxy group.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"JOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 21(1):48-58 (2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Ohta, Kazuchika","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000396390700007"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WORLD SCI PUBL CO INC"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1142/S1088424617500043"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1142/S1088424617500043","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 1(2017) pp. 48-58, DOI: 10.1142/S1088424617500043 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1088-4246","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11202421","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohta, Kazuchika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Adachi, Kaori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yasutake, Mikio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-01"}],"displaytype":"detail","filename":"Flying-seed-like_liquid_crystals_7.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensefree":"Electronic version of an article published as Journal of porphyrins and phthalocyanines, Volume: 21, Issues: 1(2017) pp. 48-58, DOI: 10.1142/S1088424617500043 © 2017 World Scientific Publishing Copmpany, http://www.worldscientific.com/worldscinet/jpp","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Flying-seed-like_liquid_crystals_7.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19212/files/Flying-seed-like_liquid_crystals_7.pdf"},"version_id":"94886a2e-4853-4324-a32a-f80ac162c163"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"flying-seed-like liquid crystals","subitem_subject_scheme":"Other"},{"subitem_subject":"metallomesogen","subitem_subject_scheme":"Other"},{"subitem_subject":"phthalocyanine","subitem_subject_scheme":"Other"},{"subitem_subject":"columnar mesophase","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-09-26"},"publish_date":"2017-09-26","publish_status":"0","recid":"19212","relation_version_is_last":true,"title":["Flying-seed-like liquid crystals 7(+): Synthesis and mesomorphism of novel octakis(m-chloropyridyloxy) phthalocyanato copper(II) complexes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:21:53.491439+00:00"}