{"created":"2021-03-01T06:22:17.588231+00:00","id":19213,"links":{},"metadata":{"_buckets":{"deposit":"7b705a30-24e6-44c8-903c-06ad34df9286"},"_deposit":{"id":"19213","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19213"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019213","sets":["1309:1310"]},"author_link":["104236","104237","104238"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"147","bibliographicPageStart":"130","bibliographicVolumeNumber":"648","bibliographic_titles":[{"bibliographic_title":"MOLECULAR CRYSTALS AND LIQUID CRYSTALS"}]}]},"item_6_description_19":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Published online: 28 Jun 2017","subitem_description_type":"Other"}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have synthesized a series of six novel bis(beta-diketonate)copper (II) complexes, 1a, 1b, 2a, 2b, 3a, and 3b, substituted by two bulky substituents in the short molecular axis direction to investigate their mesomorphism. The m, p, m'-trimethoxylphenyl-substituted derivatives, 2a and 2b, and the m, p-dimethoxylphenyl-substituted derivatives, 3a and 3b, did not show mesomorphism, whereas each of the p-methoxyphenyl-substituted derivatives 1a and 1b only showed a nematic phase, which was revealed from polarizing microscopic observations. We established from X-ray diffraction and Z-value calculations that each of the crank-like derivatives 1a and 1b forms a rectangular parallelepiped dimer and shows a biaxial nematic phase.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"MOLECULAR CRYSTALS AND LIQUID CRYSTALS. 648(1):130-147 (2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Ohta, Kazuchika","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000404578800011"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"TAYLOR & FRANCIS LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1080/15421406.2017.1301922"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1080/15421406.2017.1301922","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Crystals and Liquid Crystals on 2017, available online: http://www.tandfonline.com/10.1080/15421406.2017.1301922 ."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1542-1406","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11836169","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kanai, Yoriko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Akimoto, Hajime"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta, Kazuchika"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-28"}],"displaytype":"detail","filename":"Biaxial_nematic_phase_of_crank-like_bis_beta-diketonato.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensefree":"This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Crystals and Liquid Crystals on 2017, available online: http://www.tandfonline.com/10.1080/15421406.2017.1301922 .","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Biaxial_nematic_phase_of_crank-like_bis_beta-diketonato.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19213/files/Biaxial_nematic_phase_of_crank-like_bis_beta-diketonato.pdf"},"version_id":"30b44838-da4e-4b89-a1e8-dc561985963b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Biaxial nematic phase","subitem_subject_scheme":"Other"},{"subitem_subject":"Bis(beta-diketonato)copper(II)complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"Metallomesogen","subitem_subject_scheme":"Other"},{"subitem_subject":"Short title: Biaxial LC of 8-diketonato Cu complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"X-ray diffraction","subitem_subject_scheme":"Other"},{"subitem_subject":"Z-value calculations","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Biaxial nematic phase of crank-like bis(beta-diketonato) copper(II) complexes established by X-ray diffraction and Z-value calculations","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Biaxial nematic phase of crank-like bis(beta-diketonato) copper(II) complexes established by X-ray diffraction and Z-value calculations","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-09-26"},"publish_date":"2017-09-26","publish_status":"0","recid":"19213","relation_version_is_last":true,"title":["Biaxial nematic phase of crank-like bis(beta-diketonato) copper(II) complexes established by X-ray diffraction and Z-value calculations"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:27:28.461492+00:00"}