@article{oai:soar-ir.repo.nii.ac.jp:00019434, author = {髙坂, 泰弘 and 北山, 辰樹}, issue = {3}, journal = {日本ゴム協会誌}, month = {}, note = {Stereospecific living anionic polymerizations of methyl methacrylate are described with the focus on precise control of polymer structures such as molecular weight and its dispersity, tacticity and end-groups. In particular, recently developed efficient termination reaction with α-(chloromethyl) acrylates is discussed, which affords stereoregular poly(methyl methacrylate)s possessing α,β-unsaturated esters at the ω-ends. The subsequent thiol-ene click reaction resulted in a quantitative end-functionalization. The terminating reaction is also useful to evaluate reactivity of monomers and stereospecificity of propagating species in the presence of some additives., Article, 日本ゴム協会誌.88(3):80-85(2015)}, pages = {80--85}, title = {メタクリル酸メチルの精密アニオン重合 -分子量,立体規則性,末端構造の三元同時制御-}, volume = {88}, year = {2015} }