{"created":"2021-03-01T06:22:31.103044+00:00","id":19434,"links":{},"metadata":{"_buckets":{"deposit":"a85fccde-e468-45a0-8640-932800be807f"},"_deposit":{"id":"19434","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19434"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019434","sets":["1309:1310"]},"author_link":["104926","104927"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Precise Anionic Polymerization of Methyl Methacrylate: Simultaneous Control of Molecular Weight, Stereoregularity, and End-Structure"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"85","bibliographicPageStart":"80","bibliographicVolumeNumber":"88","bibliographic_titles":[{"bibliographic_title":"日本ゴム協会誌"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Stereospecific living anionic polymerizations of methyl methacrylate are described with the focus on precise control of polymer structures such as molecular weight and its dispersity, tacticity and end-groups. In particular, recently developed efficient termination reaction with α-(chloromethyl) acrylates is discussed, which affords stereoregular poly(methyl methacrylate)s possessing α,β-unsaturated esters at the ω-ends. The subsequent thiol-ene click reaction resulted in a quantitative end-functionalization. The terminating reaction is also useful to evaluate reactivity of monomers and stereospecificity of propagating species in the presence of some additives.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"日本ゴム協会誌.88(3):80-85(2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"髙坂, 泰弘","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本ゴム協会誌"}]},"item_6_relation_46":{"attribute_name":"他の資源との関係：URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://www.jstage.jst.go.jp/browse/gomu/-char/ja"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/gomu/-char/ja","subitem_relation_type_select":"URI"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.2324/gomu.88.80"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.2324/gomu.88.80","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0029-022X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00189720","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"髙坂, 泰弘"}],"nameIdentifiers":[{"nameIdentifier":"104926","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"北山, 辰樹"}],"nameIdentifiers":[{"nameIdentifier":"104927","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-22"}],"displaytype":"detail","filename":"26620105_05.pdf","filesize":[{"value":"804.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"26620105_05.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19434/files/26620105_05.pdf"},"version_id":"e4484563-5eee-4463-810c-ab999631d917"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Living Anionic Ploymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereoregularity","subitem_subject_scheme":"Other"},{"subitem_subject":"End-functionalization","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereospecific Polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"Tacticity","subitem_subject_scheme":"Other"},{"subitem_subject":"Click Chemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"メタクリル酸メチルの精密アニオン重合 －分子量，立体規則性，末端構造の三元同時制御－","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"メタクリル酸メチルの精密アニオン重合 －分子量，立体規則性，末端構造の三元同時制御－","subitem_title_language":"ja"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-01-22"},"publish_date":"2018-01-22","publish_status":"0","recid":"19434","relation_version_is_last":true,"title":["メタクリル酸メチルの精密アニオン重合 －分子量，立体規則性，末端構造の三元同時制御－"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:27:30.169342+00:00"}