{"created":"2021-03-01T06:22:40.342793+00:00","id":19580,"links":{},"metadata":{"_buckets":{"deposit":"58d3b5c5-121d-44d1-8853-102398770fca"},"_deposit":{"id":"19580","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19580"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019580","sets":["1221:1222"]},"author_link":["105106","105107","105108","105109","105110"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"455","bibliographicPageStart":"449","bibliographicVolumeNumber":"47","bibliographic_titles":[{"bibliographic_title":"POLYMER JOURNAL"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Porous thin-film polymethylsiloxane microparticles have been prepared successfully from octyltrichlorosilane and methyltrichlorosilane in (water/oil) W/O emulsion systems by using several oil phases and changing the amount of the silanes or of the surfactant Span 60. Hollow microspheres of various shell thicknesses (120-180 nm) and high surface area were prepared by using four types of nonpolar solvents as the oil phase of the W/O emulsion system. The diameter of the spheres can also be controlled (1-1.6 mu m) by using different oil phases. The results of thermal analysis, nitrogen adsorption isotherm, infrared spectra and X-ray diffraction data showed that hollow microspheres of amorphous polymethylsiloxane with high surface area (360-385 m(2)g(-1)) can be obtained by heating the spheres in air at 673 K; the polymethylsiloxane microspheres become nonporous silica particles after calcination at 873 K for 3 h. Cup-shape microparticles of polymethylsiloxane with nano-order thickness (20-120 nm) were prepared by reducing the amount of silanes in the mixture. Small hollow particles were prepared by replacing a portion of the octyltrichlorosilane with Span 60.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"POLYMER JOURNAL. 47(6): 449-455 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Okada, Tomohiko","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html"},{"subitem_link_text":"Sakai, Toshio","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"},{"subitem_link_text":"Haeiwa, Tetsuji","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.ZNkeZVkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000355744300007"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"NATURE PUBLISHING GROUP"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1038/pj.2015.16"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1038/pj.2015.16","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright© 2015 The Society of Polymer Science, Japan"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0032-3896","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Mishima, Shozi"}],"nameIdentifiers":[{"nameIdentifier":"105106","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okada, Tomohiko"}],"nameIdentifiers":[{"nameIdentifier":"105107","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakai, Toshio"}],"nameIdentifiers":[{"nameIdentifier":"105108","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kiyono, Ryutaro"}],"nameIdentifiers":[{"nameIdentifier":"105109","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Haeiwa, Tetsuji"}],"nameIdentifiers":[{"nameIdentifier":"105110","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-03-09"}],"displaytype":"detail","filename":"Preparation_of_porous_thin-film_polymethylsiloxane_microparticles_in_a_WO_emulsion_system.pdf","filesize":[{"value":"219.6 kB"}],"format":"application/pdf","licensefree":"Copyright© 2015 The Society of Polymer Science, Japan","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Preparation_of_porous_thin-film_polymethylsiloxane_microparticles_in_a_WO_emulsion_system.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19580/files/Preparation_of_porous_thin-film_polymethylsiloxane_microparticles_in_a_WO_emulsion_system.pdf"},"version_id":"e54e6611-2ea8-4351-8583-473c4d0b913c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparation of porous thin-film polymethylsiloxane microparticles in a W/O emulsion system","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparation of porous thin-film polymethylsiloxane microparticles in a W/O emulsion system","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-03-09"},"publish_date":"2018-03-09","publish_status":"0","recid":"19580","relation_version_is_last":true,"title":["Preparation of porous thin-film polymethylsiloxane microparticles in a W/O emulsion system"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:01:04.586420+00:00"}