{"created":"2021-03-01T06:22:58.920007+00:00","id":19879,"links":{},"metadata":{"_buckets":{"deposit":"481c9c71-9b89-4147-84fb-077d7ab9b3c2"},"_deposit":{"id":"19879","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19879"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019879","sets":["1169:1170"]},"author_link":["105691","105692","105693","105694"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"5730","bibliographicPageStart":"5721","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"CHEMISTRY-A EUROPEAN JOURNAL"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1-, 2-, and 6-(Ferrocenylethynyl)azulene derivatives 1016 have been prepared by palladium-catalyzed alkynylation of ethynylferrocene with the corresponding haloazulenes under SonogashiraHagihara conditions. Compounds 1016 reacted with tetracyanoethylene (TCNE) in a [2+2] cycloadditioncycloreversion reaction to afford the corresponding 2-azulenyl-1,1,4,4,-tetracyano-3-ferrocenyl-1,3-butadiene chromophores 1723 in excellent yields. The redox behavior of the novel azulene chromophores 1723 was examined by using cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, a significant color change was observed by visible spectroscopy under electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"CHEMISTRY-A EUROPEAN JOURNAL. 19(18):5721-5730 (2013)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000318282200029"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_47":{"attribute_name":"PubMed","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"23447514"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=23447514","subitem_relation_type_select":"PMID"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/chem.201202257"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201202257","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Shoji, T. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis of 2‐Azulenyl‐1,1,4,4‐tetracyano‐3‐ferrocenyl‐1,3‐butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 19: 5721-5730. doi:10.1002/chem.201202257, which has been published in final form at |https://doi.org/10.1002/chem.201202257 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11076269","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Morita, Noboru"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Chem_Eur_J_19_5721-5730.pdf","filesize":[{"value":"607.4 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: Shoji, T. , Ito, S. , Okujima, T. and Morita, N. (2013), Synthesis of 2‐Azulenyl‐1,1,4,4‐tetracyano‐3‐ferrocenyl‐1,3‐butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene. Chem. Eur. J., 19: 5721-5730. doi:10.1002/chem.201202257, which has been published in final form at |https://doi.org/10.1002/chem.201202257 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Chem_Eur_J_19_5721-5730.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19879/files/Chem_Eur_J_19_5721-5730.pdf"},"version_id":"c2217026-8213-46c9-9e03-a9506b05da50"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"azulene","subitem_subject_scheme":"Other"},{"subitem_subject":"cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"donoracceptor systems","subitem_subject_scheme":"Other"},{"subitem_subject":"electrochemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"ferrocene","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19879","relation_version_is_last":true,"title":["Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T03:45:51.791244+00:00"}