{"created":"2021-03-01T06:22:58.981226+00:00","id":19880,"links":{},"metadata":{"_buckets":{"deposit":"306ef22b-fb6b-453e-928c-be4144917dcc"},"_deposit":{"id":"19880","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19880"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019880","sets":["1169:1170"]},"author_link":["105695","105696","105697","105698","105699","105700","105701","105702"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"34","bibliographicPageEnd":"7799","bibliographicPageStart":"7785","bibliographicVolumeNumber":"2013","bibliographic_titles":[{"bibliographic_title":"EUROPEAN JOURNAL OF ORGANIC CHEMISTRY"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1-Ethynylazulenes connected by several arylamine cores reacted with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2+2] cycloaddition-cycloreversion reaction to afford the corresponding tetracyanobutadiene (TCBD) and dicyanoquinodimethane (DCNQ) chromophores, respectively, in excellent yields. The intramolecular charge-transfer (ICT) characters between the donor (azulene and arylamine cores) and acceptor (TCBD and DCNQ units) moieties were investigated by UV/Vis spectroscopy and theoretical calculations. The redox behavior of the new TCBD and DCNQ derivatives was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2013(34):7785-7799 (2013)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000332831100005"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/ejoc.201301006"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/ejoc.201301006","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Shoji, T. , Shimomura, E. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. , Toyota, K. and Morita, N. (2013), Synthesis and Properties of Azulene‐Substituted Donor–Acceptor Chromophores Connected by Arylamine Cores. Eur. J. Org. Chem., 2013: 7785-7799. doi:10.1002/ejoc.201301006, which has been published in final form at https://doi.org/10.1002/ejoc.201301006 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1434-193X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1118165X","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimomura, Erika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Mitsuhisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Akifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Toyota, Kozo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Morita, Noboru"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Eur_J_Org_Chem_2013_7785-7799.pdf","filesize":[{"value":"651.3 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: Shoji, T. , Shimomura, E. , Maruyama, M. , Maruyama, A. , Ito, S. , Okujima, T. , Toyota, K. and Morita, N. (2013), Synthesis and Properties of Azulene‐Substituted Donor–Acceptor Chromophores Connected by Arylamine Cores. Eur. J. Org. Chem., 2013: 7785-7799. doi:10.1002/ejoc.201301006, which has been published in final form at https://doi.org/10.1002/ejoc.201301006 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Eur_J_Org_Chem_2013_7785-7799.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19880/files/Eur_J_Org_Chem_2013_7785-7799.pdf"},"version_id":"df199056-2ebf-411a-b490-3e882cae0707"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Arenes","subitem_subject_scheme":"Other"},{"subitem_subject":"Chromophores","subitem_subject_scheme":"Other"},{"subitem_subject":"Cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"Redox chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclic voltammetry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and Properties of Azulene-Substituted Donor-Acceptor Chromophores Connected by Arylamine Cores","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and Properties of Azulene-Substituted Donor-Acceptor Chromophores Connected by Arylamine Cores","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19880","relation_version_is_last":true,"title":["Synthesis and Properties of Azulene-Substituted Donor-Acceptor Chromophores Connected by Arylamine Cores"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:16:28.377507+00:00"}