{"created":"2021-03-01T06:22:59.227099+00:00","id":19884,"links":{},"metadata":{"_buckets":{"deposit":"d977c93f-00e6-4fca-a92a-62606600740a"},"_deposit":{"id":"19884","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19884"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019884","sets":["1169:1170"]},"author_link":["105720","105721","105722","105723","105724","105725","105726"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-01-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"409","bibliographicPageStart":"402","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"CHEMISTRY-A EUROPEAN JOURNAL"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Aryl-substituted 1,1,4,4-tetracyano-1,3-butadienes (FcTCBDs) and bis(1,1,4,4-tetracyanobutadiene)s (bisFcTCBDs), possessing a ferrocenyl group on each terminal, were prepared by the reaction of a variety of alkynes with tetracyanoethylene (TCNE) in a [2+2] cycloaddition reaction, followed by retro-electrocyclization of the initially formed [2+2] cycloadducts (i.e., cyclobutene derivatives). The characteristic intramolecular charge transfer (ICT) between the donor (ferrocene) and acceptor (TCBD) moieties were investigated by using UV/ Vis spectroscopy. The redox behaviors of FcTCBDs and bis-FcTCBDs were examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their properties of multi-electron transfer depending on the number of ferrocene and TCBD moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"CHEMISTRY-A EUROPEAN JOURNAL. 23(21):402-409 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000346735000043"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_47":{"attribute_name":"PubMed","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"25370830"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=25370830","subitem_relation_type_select":"PMID"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/chem.201405004"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201405004","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Yaku, C. , Kamata, N. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of 1,1,4,4‐Tetracyano‐2‐ferrocenyl‐1,3‐butadienes Connected by Aryl, Biaryl, and Teraryl Spacers. Chem. Eur. J., 21: 402-409. doi:10.1002/chem.201405004, which has been published in final form at https://doi.org/10.1002/chem.201405004 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11076269","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{"nameIdentifier":"105720","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maruyama, Akifumi"}],"nameIdentifiers":[{"nameIdentifier":"105721","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yaku, Chisa"}],"nameIdentifiers":[{"nameIdentifier":"105722","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamata, Natsumi"}],"nameIdentifiers":[{"nameIdentifier":"105723","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{"nameIdentifier":"105724","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{"nameIdentifier":"105725","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Toyota, Kozo"}],"nameIdentifiers":[{"nameIdentifier":"105726","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Chem_Eur_J_21_402-409.pdf","filesize":[{"value":"478.3 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Yaku, C. , Kamata, N. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of 1,1,4,4‐Tetracyano‐2‐ferrocenyl‐1,3‐butadienes Connected by Aryl, Biaryl, and Teraryl Spacers. Chem. Eur. J., 21: 402-409. doi:10.1002/chem.201405004, which has been published in final form at https://doi.org/10.1002/chem.201405004 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Chem_Eur_J_21_402-409.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19884/files/Chem_Eur_J_21_402-409.pdf"},"version_id":"df273a31-db17-4fa5-ae6d-e2301d6abf42"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"chromophores","subitem_subject_scheme":"Other"},{"subitem_subject":"cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"donor-acceptor systems","subitem_subject_scheme":"Other"},{"subitem_subject":"ferrocene","subitem_subject_scheme":"Other"},{"subitem_subject":"redox chemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19884","relation_version_is_last":true,"title":["Synthesis, Properties, and Redox Behavior of 1,1,4,4-Tetracyano-2-ferrocenyl-1,3-butadienes Connected by Aryl, Biaryl, and Teraryl Spacers"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T03:46:02.391209+00:00"}