@article{oai:soar-ir.repo.nii.ac.jp:00019885,
 author = {Shoji, Taku and Maruyama, Akifumi and Shimomura, Erika and Nagai, Daichi and Ito, Shunji and Okujima, Tetsuo and Toyota, Kozo},
 issue = {9},
 journal = {EUROPEAN JOURNAL OF ORGANIC CHEMISTRY},
 month = {Mar},
 note = {Tris(1-azulenylacetylene) and tris(1-azulenylethynylarylacetylene) chromophores connected to a 1,3,5-tri(1-azulenyl)benzene core have been prepared by the Pd-catalyzed alkynylations of 1-ethynylazulene with tris(3-iodo-1-azulenyl)benzene or iodoarene derivatives substituted with a 1-azulenylethynyl group with tris(3-ethynyl-1-azulenyl)benzene under Sonogashira-Hagihara cross-coupling conditions. These compounds reacted with tetracyanoethylene in formal [2+2] cycloaddition-retroelectrocyclization reactions to afford the corresponding tris(1-azulenyltetracyanobutadiene) and tris[1-azulenylbis(tetracyanobutadiene)] chromophores in excellent yields. The redox behavior of the tetracyanobutadiene (TCBD) derivatives was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions., Article, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2015(9):1979-1990 (2015)},
 pages = {1979--1990},
 title = {Synthesis, Properties, and Redox Behavior of Tris-(1-azulenyltetracyanobutadiene) and Tris[1-azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5-Tri(1-azulenyl)benzene Core},
 volume = {2015},
 year = {2015}
}