{"created":"2021-03-01T06:22:59.290115+00:00","id":19885,"links":{},"metadata":{"_buckets":{"deposit":"de07d207-633c-4dcc-a501-c64eb1561bb7"},"_deposit":{"id":"19885","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19885"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019885","sets":["1169:1170"]},"author_link":["105727","105728","105729","105730","105731","105732","105733"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"1990","bibliographicPageStart":"1979","bibliographicVolumeNumber":"2015","bibliographic_titles":[{"bibliographic_title":"EUROPEAN JOURNAL OF ORGANIC CHEMISTRY"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Tris(1-azulenylacetylene) and tris(1-azulenylethynylarylacetylene) chromophores connected to a 1,3,5-tri(1-azulenyl)benzene core have been prepared by the Pd-catalyzed alkynylations of 1-ethynylazulene with tris(3-iodo-1-azulenyl)benzene or iodoarene derivatives substituted with a 1-azulenylethynyl group with tris(3-ethynyl-1-azulenyl)benzene under Sonogashira-Hagihara cross-coupling conditions. These compounds reacted with tetracyanoethylene in formal [2+2] cycloaddition-retroelectrocyclization reactions to afford the corresponding tris(1-azulenyltetracyanobutadiene) and tris[1-azulenylbis(tetracyanobutadiene)] chromophores in excellent yields. The redox behavior of the tetracyanobutadiene (TCBD) derivatives was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2015(9):1979-1990 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000351207100015"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/ejoc.201403556"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/ejoc.201403556","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Shimomura, E. , Nagai, D. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of Tris(1‐azulenyltetracyanobutadiene) and Tris[1‐azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5‐Tri(1‐azulenyl)benzene Core. Eur. J. Org. Chem., 2015: 1979-1990. doi:10.1002/ejoc.201403556, which has been published in final form at https://doi.org/10.1002/ejoc.201403556 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1434-193X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1118165X","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Akifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimomura, Erika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagai, Daichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Toyota, Kozo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Eur_J_Org_Chem_2015_1979-1990.pdf","filesize":[{"value":"915.6 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: Shoji, T. , Maruyama, A. , Shimomura, E. , Nagai, D. , Ito, S. , Okujima, T. and Toyota, K. (2015), Synthesis, Properties, and Redox Behavior of Tris(1‐azulenyltetracyanobutadiene) and Tris[1‐azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5‐Tri(1‐azulenyl)benzene Core. Eur. J. Org. Chem., 2015: 1979-1990. doi:10.1002/ejoc.201403556, which has been published in final form at https://doi.org/10.1002/ejoc.201403556 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Eur_J_Org_Chem_2015_1979-1990.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19885/files/Eur_J_Org_Chem_2015_1979-1990.pdf"},"version_id":"64ac6461-e2cc-4658-983c-0495c80f0f7b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Redox chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"Donor-acceptor systems","subitem_subject_scheme":"Other"},{"subitem_subject":"Azulenes","subitem_subject_scheme":"Other"},{"subitem_subject":"Cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"Chromophores","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, Properties, and Redox Behavior of Tris-(1-azulenyltetracyanobutadiene) and Tris[1-azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5-Tri(1-azulenyl)benzene Core","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, Properties, and Redox Behavior of Tris-(1-azulenyltetracyanobutadiene) and Tris[1-azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5-Tri(1-azulenyl)benzene Core","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19885","relation_version_is_last":true,"title":["Synthesis, Properties, and Redox Behavior of Tris-(1-azulenyltetracyanobutadiene) and Tris[1-azulenylbis(tetracyanobutadiene)] Chromophores Connected to a 1,3,5-Tri(1-azulenyl)benzene Core"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:16:28.963373+00:00"}