{"created":"2021-03-01T06:22:59.351638+00:00","id":19886,"links":{},"metadata":{"_buckets":{"deposit":"6ce0e97a-895a-4706-8679-d8a593b03b07"},"_deposit":{"id":"19886","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19886"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019886","sets":["1169:1170"]},"author_link":["105734","105735","105736","105737","105738","105739","105740","105741","105742","105743"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"57","bibliographicPageStart":"49","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"CHEMISTRYSELECT"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Tris[(3-phenyl-1-azulenyl) tetracyanobutadiene] s and tris(arylte-tracyanobutadiene) s connected to a 1,3,5-tri(1-azulenyl) benzene core (tris-AzTCBDs) have been prepared by the Pd-catalyzed alkynylation of tris(3-iodo-1-azulenyl) benzene derivative with the corresponding 1-ethynylazulene or ethynylbenzene derivatives under Sonogashira-Hagihara cross-coupling conditions, followed by the reaction with tetracyanoethylene (TCNE) in a formal [ 2 + 2] cycloaddition-retroelectrocyclization (CA-RE) reaction. The intramolecular charge-transfer (ICT) interactions of the new chromophores were investigated by the comparison with those of the model tetracyanobutadiene de-rivatives with azulene substituents (AzTCBDs), which were prepared by the reaction of the corresponding 1-ethynylazulene derivative with iodoarenes, followed by the CA-RE reaction with TCNE, utilizing UV/Vis spectroscopy and theoretical calculations. The redox behavior of the alkyne precursors and the tetracyanobutadiene derivatives was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, significant color changes of these compounds were observed by visible spectroscopy under the electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"CHEMISTRYSELECT. 9:49-57 (2016)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000392410300009"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/slct.201500036"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/slct.201500036","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: T. Shoji , A. Maruyama, M. Tanaka, D. Nagai, E. Shimomura, K. Fujimori, S. Ito, T. Okujima, K. Toyota, M. Yasunami (the late), ChemistrySelect 2016, 1, 49. , which has been published in final form at https://doi.org/10.1002/slct.201500036 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2365-6549","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Akifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Miwa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagai, Daichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimomura, Erika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimori, Kunihide"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Toyota, Kozo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yasunami, Masafumi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"ChemistrySelect2016_1_49.pdf","filesize":[{"value":"714.6 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: T. Shoji , A. Maruyama, M. Tanaka, D. Nagai, E. Shimomura, K. Fujimori, S. Ito, T. Okujima, K. Toyota, M. Yasunami (the late), ChemistrySelect 2016, 1, 49. , which has been published in final form at https://doi.org/10.1002/slct.201500036 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ChemistrySelect2016_1_49.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19886/files/ChemistrySelect2016_1_49.pdf"},"version_id":"40cce4d3-3235-407e-abb2-6f3d0fb9b961"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Azulene","subitem_subject_scheme":"Other"},{"subitem_subject":"Donor-acceptor chromophores","subitem_subject_scheme":"Other"},{"subitem_subject":"Cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"UV/Vis spectrum","subitem_subject_scheme":"Other"},{"subitem_subject":"Redox chemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and Properties of (3-Phenyl-1-azulenyl) tetracyanobetadienes and Tris(aryltetracyanobetadiene) s Connected with 1,3,5-Tri(1-azulenyl) benzene Core","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and Properties of (3-Phenyl-1-azulenyl) tetracyanobetadienes and Tris(aryltetracyanobetadiene) s Connected with 1,3,5-Tri(1-azulenyl) benzene Core","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19886","relation_version_is_last":true,"title":["Synthesis and Properties of (3-Phenyl-1-azulenyl) tetracyanobetadienes and Tris(aryltetracyanobetadiene) s Connected with 1,3,5-Tri(1-azulenyl) benzene Core"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:38:24.596673+00:00"}