{"created":"2021-03-01T06:22:59.535589+00:00","id":19889,"links":{},"metadata":{"_buckets":{"deposit":"5c061c37-0221-45d6-8079-303e57761ec0"},"_deposit":{"id":"19889","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19889"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019889","sets":["1169:1170"]},"author_link":["105758","105759","105760","105761","105762","105763","105764","105765","105766"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-05-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"3923","bibliographicPageStart":"3917","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"ORGANIC & BIOMOLECULAR CHEMISTRY"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The SNAr reaction of 2-chloroazulene derivative 1 with ethoxycarbonyl groups at the 1,3-positions of the azulene ring with several amines afforded the corresponding 2-aminoazulenes 3-9 in excellent yields. 2-Chloroazulene (2) without the electron-withdrawing groups reacted with highly nucleophilic cyclic amines (i.e., morpholine, piperidine and pyrrolidine) under the high-temperature conditions in a sealed tube to produce the corresponding 2-aminoazulenes 10-12 in good yields. 2-Aminoazulenes 10-14 without the electron-withdrawing groups were also obtained in good yields by the treatment of compounds 3-7 with 100% H3PO4, but in the cases of the reaction of 8 and 9 with a secondary amine function, the decomposition of the products resulted. The synthesis of 2-arylazoazulenes 15-18 was also established via the SNAr reaction of 1 with arylhydrazines. The optical and electrochemical properties of the 2-arylazoazulene derivatives were examined by UV/Vis spectroscopy, theoretical calculations and voltammetric experiments.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"ORGANIC & BIOMOLECULAR CHEMISTRY. 94(10):3917-3923 (2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"},{"subitem_link_text":"Ohta, Akira","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000401147200015"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ROYAL SOC CHEMISTRY"}]},"item_6_relation_47":{"attribute_name":"PubMed","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"28426084"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28426084","subitem_relation_type_select":"PMID"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/c7ob00691h"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/c7ob00691h","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017 Royal Society of Chemistry"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1477-0520","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1168650X","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sugiyama, Shuhei"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Araki, Takanori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta, Akira"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sekiguchi, Ryuta"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Shigeki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yasunami, Masafumi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Org_Biomol_Chem_15_3917-3923.pdf","filesize":[{"value":"444.9 kB"}],"format":"application/pdf","licensefree":"© 2017 Royal Society of Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Org_Biomol_Chem_15_3917-3923.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19889/files/Org_Biomol_Chem_15_3917-3923.pdf"},"version_id":"28d06640-f8c5-41e2-b205-360231279e89"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19889","relation_version_is_last":true,"title":["Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:16:30.416870+00:00"}