{"created":"2021-03-01T06:22:59.659913+00:00","id":19891,"links":{},"metadata":{"_buckets":{"deposit":"2e0e6006-4dc0-473b-a28f-7cc0141a9f61"},"_deposit":{"id":"19891","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19891"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019891","sets":["1169:1170"]},"author_link":["105769","105770","105771","105772","105773","105774","105775","105776","105777"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-04-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"5136","bibliographicPageStart":"5126","bibliographicVolumeNumber":"23","bibliographic_titles":[{"bibliographic_title":"CHEMISTRY-A EUROPEAN JOURNAL"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Synthesis of 2-aminofuran derivatives with an azulene or N,N-dimethylanilino substituent was established by the formal [2+2] cycloaddition-retroelectrocyclization of 3-(1-azulenyl or N,N-dimethylanilino)-2-propyn-1-ols with tetracyanoethylene, followed by intramolecular nucleophilic addition to the initially formed tetracyanobutadiene moiety of the internal hydroxyl group that come from 2-propyn-1-ol. The reaction proceeds under mild conditions with short reaction period. The products of the reaction are readily available through a simple purification procedure. 2-Aminofuran derivatives obtained by this reaction could be converted into 6-aminofulvene derivatives upon reaction with various amines. The structures of 2-aminofuran and 6-aminopentafulvene with a N,N-dimethylanilino substituent were confirmed by single-crystal X-ray structural analysis.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"CHEMISTRY-A EUROPEAN JOURNAL. 23(21):5126-5136 (2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"},{"subitem_link_text":"Ohta, Akira","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000399327400023"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_47":{"attribute_name":"PubMed","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"28191692"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=28191692","subitem_relation_type_select":"PMID"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/chem.201700121"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201700121","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: T. Shoji, D. Nagai, M. Tanaka, T. Araki, A. Ohta, R. Sekiguchi, S. Ito, S. Mori, T. Okujima, Chem. Eur. J. 2017, 23, 5126., which has been published in final form at https://doi.org/10.1002/chem.201700121 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11076269","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{"nameIdentifier":"105769","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagai, Daichi"}],"nameIdentifiers":[{"nameIdentifier":"105770","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tanaka, Miwa"}],"nameIdentifiers":[{"nameIdentifier":"105771","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Araki, Takanori"}],"nameIdentifiers":[{"nameIdentifier":"105772","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohta, Akira"}],"nameIdentifiers":[{"nameIdentifier":"105773","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sekiguchi, Ryuta"}],"nameIdentifiers":[{"nameIdentifier":"105774","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{"nameIdentifier":"105775","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mori, Shigeki"}],"nameIdentifiers":[{"nameIdentifier":"105776","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{"nameIdentifier":"105777","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"Chem_Eur_J_2017_23_5126.pdf","filesize":[{"value":"931.8 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: T. Shoji, D. Nagai, M. Tanaka, T. Araki, A. Ohta, R. Sekiguchi, S. Ito, S. Mori, T. Okujima, Chem. Eur. J. 2017, 23, 5126., which has been published in final form at https://doi.org/10.1002/chem.201700121 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Chem_Eur_J_2017_23_5126.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19891/files/Chem_Eur_J_2017_23_5126.pdf"},"version_id":"269b2f9c-784f-4c10-acd4-5106533f73b2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"azulene","subitem_subject_scheme":"Other"},{"subitem_subject":"cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"nucleophilic addition","subitem_subject_scheme":"Other"},{"subitem_subject":"oxygen heterocycles","subitem_subject_scheme":"Other"},{"subitem_subject":"synthetic methods","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19891","relation_version_is_last":true,"title":["Synthesis of 2-Aminofurans by Sequential [2+2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:16:30.822391+00:00"}