@article{oai:soar-ir.repo.nii.ac.jp:00019897, author = {Shoji, Taku and Maruyama, Mitsuhisa and Maruyama, Akifumi and Nagai, Daichi and Tanaka, Miwa and Sekiguchi, Ryuta and Ito, Shunji and Okujima, Tetsuo}, issue = {1}, journal = {HETEROCYCLES}, month = {}, note = {Azulene-substituted tetracyanobutadienes (AzTCBDs) and dicyanoquinodimethanes (AzDCNQs) connected with naphthalene cores were prepared by the reaction of 1-azulenylalkynes with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2 + 2] cycloaddition-retroelectrocyclization. The characteristic intramolecular charge transfer (ICT) characters were investigated by using UV/Vis spectroscopy and theoretical calculation. The redox behaviors of AzTCBDs and AzDCNQs were examined by cyclic voltammetry and differential pulse voltammetry, which revealed their properties of multi-electron transfer depending on the number of AzTCBD and AzDCNQ moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions., Article, HETEROCYCLES. 95(1):353-369 (2017)}, pages = {353--369}, title = {Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores}, volume = {95}, year = {2017} }