{"created":"2021-03-01T06:23:00.029034+00:00","id":19897,"links":{},"metadata":{"_buckets":{"deposit":"2b064bfd-1476-4a75-99c1-f64c572c26c3"},"_deposit":{"id":"19897","owners":[],"pid":{"revision_id":0,"type":"depid","value":"19897"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00019897","sets":["1169:1170"]},"author_link":["105821","105822","105823","105824","105825","105826","105827","105828"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"369","bibliographicPageStart":"353","bibliographicVolumeNumber":"95","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Azulene-substituted tetracyanobutadienes (AzTCBDs) and dicyanoquinodimethanes (AzDCNQs) connected with naphthalene cores were prepared by the reaction of 1-azulenylalkynes with tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in a formal [2 + 2] cycloaddition-retroelectrocyclization. The characteristic intramolecular charge transfer (ICT) characters were investigated by using UV/Vis spectroscopy and theoretical calculation. The redox behaviors of AzTCBDs and AzDCNQs were examined by cyclic voltammetry and differential pulse voltammetry, which revealed their properties of multi-electron transfer depending on the number of AzTCBD and AzDCNQ moieties. Moreover, significant color changes were observed by visible spectroscopy under the electrochemical reduction conditions.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES. 95(1):353-369 (2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shoji, Taku","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000405885400029"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.3987/COM-16-S(S)25"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3987/COM-16-S(S)25","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017 The Japan Institute of Heterocyclic Chemistry"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Taku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Mitsuhisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maruyama, Akifumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagai, Daichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Miwa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sekiguchi, Ryuta"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Shunji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okujima, Tetsuo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-13"}],"displaytype":"detail","filename":"HETEROCYCLES_95_353-369.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensefree":"© 2017 The Japan Institute of Heterocyclic Chemistry","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"HETEROCYCLES_95_353-369.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/19897/files/HETEROCYCLES_95_353-369.pdf"},"version_id":"040a4992-2f2f-4026-b3ad-e65000914cee"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Azulene","subitem_subject_scheme":"Other"},{"subitem_subject":"Naphthalene","subitem_subject_scheme":"Other"},{"subitem_subject":"2H-Cyclohepta[b]furan-2-one","subitem_subject_scheme":"Other"},{"subitem_subject":"Cycloaddition Reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemisty","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-13"},"publish_date":"2018-06-13","publish_status":"0","recid":"19897","relation_version_is_last":true,"title":["Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:38:24.849220+00:00"}