{"created":"2021-03-01T06:24:11.589427+00:00","id":21067,"links":{},"metadata":{"_buckets":{"deposit":"72046498-9df6-4eba-aea1-3b55890c6b63"},"_deposit":{"id":"21067","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21067"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021067","sets":["1221:1222"]},"author_link":["108860","108861","108862"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1133","bibliographicPageStart":"1127","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"PHYSICAL CHEMISTRY CHEMICAL PHYSICS"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Practical applications of Li-S and Li-air batteries require the morphology of the Li metal negative electrode during charge/discharge (i.e., Li-deposition/dissolution) cycling to be precisely controlled. Herein, we used magnesium bis(trifluoromethanesulfonyl)amide [Mg(TFSA)(2)] as an electrolyte additive to suppress the growth of Li dendrites, utilizing the occurrence of an alloying reaction between the initially substrate-deposited Mg and the subsequently deposited Li. Notably, no metallic Mg formation and no change in Li deposition morphology were observed at an electrolyte composition of 0.1 M Mg(TFSA)(2) + 0.9 M LiTFSA/triglyme, irrespective of the applied potential. In contrast, increasing the Mg salt concentration to 0.5 M resulted in the deposition of interconnected granules, reflecting a dramatic morphology improvement. X-ray diffraction analysis revealed the occurrence of the abovementioned alloying, which finally afforded a deposit composition of Li0.9Mg0.1 via the formation of an intermediate Li0.14Mg0.86 phase. Importantly, the deposits obtained under various applied potentials were relatively smooth, with no needle-like morphology observed.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"PHYSICAL CHEMISTRY CHEMICAL PHYSICS.20(2):1127-1133(2018)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shimizu, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html"},{"subitem_link_text":"Arai, Susumu","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jUyhbpkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000419219700044"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ROYAL SOC CHEMISTRY"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1039/c7cp06057b"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/c7cp06057b","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1463-9076","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11301773","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umeki, Makoto"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arai, Susumu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-30"}],"displaytype":"detail","filename":"16H06838_02.pdf","filesize":[{"value":"3.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"16H06838_02.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21067/files/16H06838_02.pdf"},"version_id":"3a3f5725-2240-4ce3-ae50-afaedec22ba0"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-30"}],"displaytype":"detail","filename":"16H06838_02_SupplementaryData.pdf","filesize":[{"value":"3.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"16H06838_02_SupplementaryData.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21067/files/16H06838_02_SupplementaryData.pdf"},"version_id":"69f4e662-f43e-454c-8034-19061c3e0850"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-30"},"publish_date":"2020-01-30","publish_status":"0","recid":"21067","relation_version_is_last":true,"title":["Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:18:35.563095+00:00"}