{"created":"2021-03-01T06:24:11.651498+00:00","id":21068,"links":{},"metadata":{"_buckets":{"deposit":"014ac57d-7168-4dea-a953-94a2e33a08b2"},"_deposit":{"id":"21068","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21068"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021068","sets":["1221:1222"]},"author_link":["108863","108864","108865"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-04-18","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"734","bibliographicPageStart":"727","bibliographicVolumeNumber":"47","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF APPLIED ELECTROCHEMISTRY"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Toward the realization of reliable Li-ion batteries with high performance and safety, component materials such as those of the current collector and negative electrode require further innovation. Sn, one of the most promising negative-electrode materials, can be electrochemically fixed on a substrate without any binder or conductive additive. However, the pulverization of Sn-plated films on substrates caused by large volume changes during Li-Sn reactions is the main reason hindering the practical application of Sn-plated electrodes. In the present study, we developed an electrodeposited three-dimensional (3D) Cu substrate applied to underlayer of the electrode. The effect of substrate geometry on the charge-discharge performance of the Sn electrode was investigated. The 3D-Cu/Sn electrode exhibited superior cycling performance with a reversible capacity of 470 mA h g(-1) even at the 300th cycle, whereas the Sn-plated electrode prepared on a typical flat Cu substrate showed a capacity of only 20 mA h g(-1). The results demonstrated that the 3D structure played a key role in accommodating volumetric changes in the Sn to suppress electrode disintegration. The developed 3D-Cu substrate will be significantly useful as a current collector for alloy-based active materials. [GRAPHICS] .","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"JOURNAL OF APPLIED ELECTROCHEMISTRY.47(6):727-734(2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Shimizu, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html"},{"subitem_link_text":"Arai, Susumu","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jUyhbpkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000400890300006"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"SPRINGER"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1007/s10800-017-1075-0"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1007/s10800-017-1075-0","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: https://doi.org/10.1007/s10800-017-1075-0"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-891X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11981601","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"108863","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Munkhbat, Mendsaikhan"}],"nameIdentifiers":[{"nameIdentifier":"108864","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arai, Susumu"}],"nameIdentifiers":[{"nameIdentifier":"108865","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-30"}],"displaytype":"detail","filename":"16H06838_06.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensefree":"This is a post-peer-review, pre-copyedit version of an article published in JOURNAL OF APPLIED ELECTROCHEMISTRY. The final authenticated version is available online at: https://doi.org/10.1007/s10800-017-1075-0","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"16H06838_06.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21068/files/16H06838_06.pdf"},"version_id":"c61bec91-a937-4ef9-8d8c-854889bbf62a"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-30"}],"displaytype":"detail","filename":"16H06838_06_SupplementaryData.pdf","filesize":[{"value":"764.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"16H06838_06_SupplementaryData.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21068/files/16H06838_06_SupplementaryData.pdf"},"version_id":"bb887a77-bf64-4f05-8dae-23ff74b86bc0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Electrodeposition","subitem_subject_scheme":"Other"},{"subitem_subject":"Sn electrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_scheme":"Other"},{"subitem_subject":"Three-dimensional structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Current collector","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-30"},"publish_date":"2020-01-30","publish_status":"0","recid":"21068","relation_version_is_last":true,"title":["Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:00:52.587839+00:00"}