@article{oai:soar-ir.repo.nii.ac.jp:00021113, author = {Toda, Yasunori and Shimizu, Masahiro and Iwai, Taichi and Suga, Hiroyuki}, issue = {12}, journal = {ADVANCED SYNTHESIS & CATALYSIS}, month = {Jun}, note = {An efficient method for the preparation of a range of 8-oxabicyclo[3.2.1]octane derivatives including synthetic intermediates of natural products is described, in which triethylamine effectively catalyzes [5+2] cycloaddition reactions between oxidopyrylium ylides and alkenes. This method can be applied not only to intermolecular cycloadditions with various alkenes but also to intramolecular cycloadditions. The key finding is that the combined use of organic bases having appropriate basicity and oxidopyrylium ylide precursors bearing a suitable leaving group facilitates the base-assisted generation of oxidopyrylium ylides in a catalytic manner., Article, ADVANCED SYNTHESIS & CATALYSIS.360(12):2377-2381(2018)}, pages = {2377--2381}, title = {Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8-Oxabicyclo[3.2.1]octane Frameworks}, volume = {360}, year = {2018} }