{"created":"2021-03-01T06:24:14.454723+00:00","id":21113,"links":{},"metadata":{"_buckets":{"deposit":"a120a9a3-1a6f-403b-ba00-3933be1d3e54"},"_deposit":{"id":"21113","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21113"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021113","sets":["1221:1222"]},"author_link":["108974","108975","108976","108977"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"2381","bibliographicPageStart":"2377","bibliographicVolumeNumber":"360","bibliographic_titles":[{"bibliographic_title":"ADVANCED SYNTHESIS & CATALYSIS"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An efficient method for the preparation of a range of 8-oxabicyclo[3.2.1]octane derivatives including synthetic intermediates of natural products is described, in which triethylamine effectively catalyzes [5+2] cycloaddition reactions between oxidopyrylium ylides and alkenes. This method can be applied not only to intermolecular cycloadditions with various alkenes but also to intramolecular cycloadditions. The key finding is that the combined use of organic bases having appropriate basicity and oxidopyrylium ylide precursors bearing a suitable leaving group facilitates the base-assisted generation of oxidopyrylium ylides in a catalytic manner.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"ADVANCED SYNTHESIS & CATALYSIS.360(12):2377-2381(2018)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Toda, Yasunori","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.HhkabUkh.html"},{"subitem_link_text":"Shimizu, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html"},{"subitem_link_text":"Suga, Hiroyuki","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.HmShyVfp.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000435259000018"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/adsc.201800290"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/adsc.201800290","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Toda Y. Shimizu M. Iwai T. Suga H. Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8‐Oxabicyclo[3.2.1]octane Frameworks, Advanced Synthesis & Catalysis, 10.1002/adsc.201800290, 360, 12, (2377-2381), (2018).], which has been published in final form at [https://doi.org/10.1002/adsc.201800290]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1615-4150","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11553845","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Toda, Yasunori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Iwai, Taichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suga, Hiroyuki"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-27"}],"displaytype":"detail","filename":"15K05497_01.pdf","filesize":[{"value":"191.9 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: [Toda Y. Shimizu M. Iwai T. Suga H. Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8‐Oxabicyclo[3.2.1]octane Frameworks, Advanced Synthesis & Catalysis, 10.1002/adsc.201800290, 360, 12, (2377-2381), (2018).], which has been published in final form at [https://doi.org/10.1002/adsc.201800290]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15K05497_01.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21113/files/15K05497_01.pdf"},"version_id":"2d72bead-8ed4-4c6a-85ee-ed4e8922a63c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"Organic Base","subitem_subject_scheme":"Other"},{"subitem_subject":"Base Catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidopyrylium Ylide","subitem_subject_scheme":"Other"},{"subitem_subject":"Alkenes","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8-Oxabicyclo[3.2.1]octane Frameworks","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8-Oxabicyclo[3.2.1]octane Frameworks","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-02-27"},"publish_date":"2020-02-27","publish_status":"0","recid":"21113","relation_version_is_last":true,"title":["Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8-Oxabicyclo[3.2.1]octane Frameworks"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:18:31.935094+00:00"}