@article{oai:soar-ir.repo.nii.ac.jp:00021114, author = {Suga, Hiroyuki and Iwai, Taichi and Shimizu, Masahiro and Takahashi, Kie and Toda, Yasunori}, issue = {9}, journal = {CHEMICAL COMMUNICATIONS}, month = {Jan}, note = {An efficient method for the generation of an oxidopyrylium ylide from 6-acetoxy-6-acetoxymethyl-2H-pyran-3(6H)-one using a Pd catalyst and [5+2] cycloadditions of the resulting ylide are described. Among substituted styrene derivatives as dipolarophiles, electron-rich styrenes showed higher yield (up to 80%). The [5+2] cycloaddition reactions can also be applied to exo-methylene cyclic compounds, and an improved method for the synthesis of polygalolide intermediate has been demonstrated., Article, CHEMICAL COMMUNICATIONS.54(9):1109-1112(2018)}, pages = {1109--1112}, title = {Efficient generation of an oxidopyrylium ylide using a Pd catalyst and its [5+2] cycloadditions with several dipolarophiles}, volume = {54}, year = {2018} }