{"created":"2021-03-01T06:24:20.621738+00:00","id":21212,"links":{},"metadata":{"_buckets":{"deposit":"e30fc71b-c39a-4d00-8717-ad150704a1c5"},"_deposit":{"id":"21212","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21212"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021212","sets":["1309:1310"]},"author_link":["109149","109150","109151"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"549","bibliographicPageStart":"539","bibliographicVolumeNumber":"67","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF OLEO SCIENCE"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"D,L-Methionine was chosen as a starting material for the preparation of a new gelator N-10-undecenoyl-D,L-methionylaminooctadecane (DL-Met-R-18). Three oligo (dimethylsiloxane)-containing gelators, DL-Met-R-18/Si-3 DL-Met-R-18/Si7-8, and DL-Met-R-18/Si14-159 were also prepared from DL-Met-R-18 by hydrosilylation reactions. Their gelation abilities were evaluated on the basis of the minimum gel concentration using nine solvents. Compound DL-Met-R-18 was able to gelate liquid paraffin and silicone oil, but it crystallized in most solvents. However, DL-Met-R-18/Si7-8 resulted to be the best gelator, gelling eight solvents at low concentrations. The results of gelation tests demonstrated that the ability to form stable gels decreases in the following order: DL-Met-R-18/Si7-8 approximate to DL-Met-R-18/Si14-15 > DL-Met-R-18/Si-3 >> DL-Met-R-18. The aspects and thermal stabilities of the gels were investigated using three-component mixtures of solvents composed of hexadecyl 2-ethylhexanoate, liquid paraffin, and decamethylcyclopentasiloxane (66 combinations). DL-Met-R-18/Si-3, DL-Met-R-18/Si7-8, and DL-Met-R-18/Si14-15 could form gels with all these mixed solvent combinations; particularly, DL-Met-R-18/Si7-8, gave rise to transparent or translucent gels. FT-IR spectra suggested that the formation of hydrogen bonds between the NH and C=O groups of the amides is one of driving forces involved in the gelation process. Aggregates comprising three-dimensional networks were studied by transmission electron microscopy. Moreover, the viscoelastic behavior of the gels was investigated by rheology measurements.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"JOURNAL OF OLEO SCIENCE.67(5):539-549(2018)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Suzuki, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"},{"subitem_link_text":"Hanabusa, Kenji","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000431475000006"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"JAPAN OIL CHEMISTS SOC"}]},"item_6_relation_46":{"attribute_name":"他の資源との関係：URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://www.jstage.jst.go.jp/article/jos/67/5/67_ess17248/_pdf/-char/en"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/article/jos/67/5/67_ess17248/_pdf/-char/en","subitem_relation_type_select":"URI"}}]},"item_6_relation_47":{"attribute_name":"PubMed","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"29710040"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.ncbi.nlm.nih.gov/pubmed/29710040","subitem_relation_type_select":"PMID"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.5650/jos.ess17248"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.5650/jos.ess17248","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 by Japan Oil Chemists' Society"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1345-8957","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11503337","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suga, Shunichi"}],"nameIdentifiers":[{"nameIdentifier":"109149","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"109150","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hanabusa, Kenji"}],"nameIdentifiers":[{"nameIdentifier":"109151","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-12"}],"displaytype":"detail","filename":"15K05623_01.pdf","filesize":[{"value":"2.6 MB"}],"format":"application/pdf","licensefree":"© 2018 by Japan Oil Chemists' Society","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15K05623_01.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21212/files/15K05623_01.pdf"},"version_id":"32d2cc4c-c54e-43a7-9414-b5d8e55880ea"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"gel","subitem_subject_scheme":"Other"},{"subitem_subject":"gelator","subitem_subject_scheme":"Other"},{"subitem_subject":"gelation","subitem_subject_scheme":"Other"},{"subitem_subject":"methionine","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogen bonding","subitem_subject_scheme":"Other"},{"subitem_subject":"cosmetic","subitem_subject_scheme":"Other"},{"subitem_subject":"siloxane","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Development of New D,L-Methionine-based Gelators","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Development of New D,L-Methionine-based Gelators","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-03-12"},"publish_date":"2020-03-12","publish_status":"0","recid":"21212","relation_version_is_last":true,"title":["Development of New D,L-Methionine-based Gelators"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:18:46.490361+00:00"}