{"created":"2021-03-01T06:24:20.744521+00:00","id":21214,"links":{},"metadata":{"_buckets":{"deposit":"960fe9c5-913b-43b8-8bdc-d25fa0981976"},"_deposit":{"id":"21214","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21214"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021214","sets":["1309:1310"]},"author_link":["109157","109158","109159"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"547","bibliographicPageStart":"538","bibliographicVolumeNumber":"91","bibliographic_titles":[{"bibliographic_title":"BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Supramolecular fluorescent gelators containing a tris(beta-diketonato) complex are synthesized by using gelation-driving chelates, and their gelation abilities are studied with 15 solvents. Thin-layer films are prepared on quartz plates from the solutions and they are studied as chemosensors for amines. Fluorescence-quenching of the thin-layer films upon exposure to saturated primary and secondary amine vapors is monitored to evaluate the abilities of the chemosensors to detect amines. The morphologies of the thin-layer films are observed by transmission electron microscopy (TEM) and discussed in relation to their fluorescence-quenching. The fluorescence-quenching efficiencies upon exposure to saturated primary and secondary amines depend on the basicity and bulkiness of the amines rather than the vapor pressure. The fluorescence-quenching is caused by decomposition of a complex through nucleophilic addition of primary or secondary amines to its carbonyl group. The detection of tertiary amines is performed by monitoring the fluorescence emission from the thin-layer films, which are composed of a ligand and EuCl3. The emergence of fluorescence originates from the formation of fluorescent Eu3+-containing gelator, in which dehydrochloric acid by tertiary amines is a trigger for the complexation.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN.91(4):538-547(2018)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Suzuki, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"},{"subitem_link_text":"Hanabusa, Kenji","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000430096000005"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"CHEMICAL SOC JAPAN"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1246/bcsj.20170409"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1246/bcsj.20170409","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 The Chemical Society of Japan."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sasaki, Junpei"}],"nameIdentifiers":[{"nameIdentifier":"109157","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"109158","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hanabusa, Kenji"}],"nameIdentifiers":[{"nameIdentifier":"109159","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-12"}],"displaytype":"detail","filename":"15K05623_03.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensefree":"© 2018 The Chemical Society of Japan.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15K05623_03.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21214/files/15K05623_03.pdf"},"version_id":"614f85c3-d8a5-4640-9b58-a06814fe4af6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Detection of Amine Vapors using Luminescent Xerogels from Supramolecular Metal-Containing","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Detection of Amine Vapors using Luminescent Xerogels from Supramolecular Metal-Containing","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-03-12"},"publish_date":"2020-03-12","publish_status":"0","recid":"21214","relation_version_is_last":true,"title":["Detection of Amine Vapors using Luminescent Xerogels from Supramolecular Metal-Containing"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:18:46.534915+00:00"}