{"created":"2021-03-01T06:24:20.808332+00:00","id":21215,"links":{},"metadata":{"_buckets":{"deposit":"8a2f2f4f-a458-48f2-82a4-f873d3204c9f"},"_deposit":{"id":"21215","owners":[],"pid":{"revision_id":0,"type":"depid","value":"21215"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00021215","sets":["1309:1310"]},"author_link":["109160","109161","109162","109163","109164"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"321","bibliographicPageStart":"312","bibliographicVolumeNumber":"90","bibliographic_titles":[{"bibliographic_title":"BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Six diamides were prepared from trans-(1R,2R)-1,2-diaminocyclohexane and the corresponding racemate and were subsequently used as gelators. Three chiral compounds and their racemates were prepared. One of the chiral compounds and its racemate contained two n-dodecanoylamino groups as the same substituents. The other two chiral compounds and their racemates contained different substituents: 10-undecenoylamino and 2-heptyl-undecanoylamino groups, and 5-hydroxypentanoylamino and 2-heptylundecanoylamino groups. Their gelation abilities were evaluated on the basis of the minimum gel concentration using eight solvents. The thermal stability and transparency of the gels were investigated by UV-vis spectroscopy using three-component mixed solvents of hexadecyl 2-ethylhexanoate, liquid paraffin, and decamethyl cyclopentasiloxane (66 combinations). The gel-to-sol phase-transition temperatures were also studied. The viscoelastic behavior of the gels was studied by rheology measurements in the strain sweep mode. Aggregates constructing three-dimensional networks were studied by transmission electron microscopy and circular dichroism spectroscopy. The molecular packing of the gels was evaluated by small angle X-ray scattering (SAXS).","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN.90(3):312-321(2017)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Sato, Takaaki","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.OeLhjFkV.html"},{"subitem_link_text":"Suzuki, Masahiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"},{"subitem_link_text":"Hanabusa, Kenji","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000395700400003"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"CHEMICAL SOC JAPAN"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1246/bcsj.20160360"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1246/bcsj.20160360","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017 The Chemical Society of Japan."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakagawa, Haruka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujiki, Mamoru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sato, Takaaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suzuki, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hanabusa, Kenji"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-12"}],"displaytype":"detail","filename":"15K05623_05.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensefree":"© 2017 The Chemical Society of Japan.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15K05623_05.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/21215/files/15K05623_05.pdf"},"version_id":"3a484574-d672-43b1-9132-8e6f81e5d8ab"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characteristics of Gelation by Amides Based on trans-1,2-Diaminocyclohexane: The Importance of Different Substituents","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characteristics of Gelation by Amides Based on trans-1,2-Diaminocyclohexane: The Importance of Different Substituents","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-03-12"},"publish_date":"2020-03-12","publish_status":"0","recid":"21215","relation_version_is_last":true,"title":["Characteristics of Gelation by Amides Based on trans-1,2-Diaminocyclohexane: The Importance of Different Substituents"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:18:46.566614+00:00"}