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  1. 060 工学部
  2. 0601 学術論文

Ion-Conserving Modified Poisson-Boltzmann Theory Considering a Steric Effect in an Electrolyte

http://hdl.handle.net/10091/00022472
d963188d-33e2-4d31-b34b-50803adb91d6
名前 / ファイル ライセンス アクション
16K05650_09.pdf 16K05650_09.pdf (234.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2021-02-03
タイトル
言語 en
タイトル Ion-Conserving Modified Poisson-Boltzmann Theory Considering a Steric Effect in an Electrolyte
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Sugioka, Hideyuki

× Sugioka, Hideyuki

WEKO 110074

Sugioka, Hideyuki

Search repository
信州大学研究者総覧へのリンク
氏名 Sugioka, Hideyuki
URL https://soar-rd.shinshu-u.ac.jp/profile/ja.gpkmbUkh.html
出版者
出版者 PHYSICAL SOC JAPAN
引用
内容記述タイプ Other
内容記述 JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN.85(12):124006(2016)
書誌情報 JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN

巻 85, 号 12, p. 124006, 発行日 2016-11-24
抄録
内容記述タイプ Abstract
内容記述 The modified Poisson-Nernst-Planck (MPNP) and modified Poisson-Boltzmann (MPB) equations are well known as fundamental equations that consider a steric effect, which prevents unphysical ion concentrations. However, it is unclear whether they are equivalent or not. To clarify this problem, we propose an improved free energy formulation that considers a steric limit with an ion-conserving condition and successfully derive the ion-conserving modified Poisson-Boltzmann (IC-MPB) equations that are equivalent to the MPNP equations. Furthermore, we numerically examine the equivalence by comparing between the IC-MPB solutions obtained by the Newton method and the steady MPNP solutions obtained by the finite-element finite-volume method. A surprising aspect of our finding is that the MPB solutions are much different from the MPNP (IC-MPB) solutions in a confined space. We consider that our findings will significantly contribute to understanding the surface science between solids and liquids.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0031-9015
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00704814
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.7566/JPSJ.85.124006
関連名称
関連名称 10.7566/JPSJ.85.124006
権利
権利情報 © 2016 The Physical Society of Japan
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000389712200008
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