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An Al-doped SrTiO3 photocatalyst maintaining sunlight-driven overall water splitting activity for over 1000 h of constant illumination
http://hdl.handle.net/10091/00022537
2b2331b1-16cd-4560-85bb-6afbdd860ee8
名前 / ファイル | ライセンス | アクション | |
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This journal is ©The Royal Society of Chemistry 2019. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-02-16 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | An Al-doped SrTiO3 photocatalyst maintaining sunlight-driven overall water splitting activity for over 1000 h of constant illumination | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Lyu, Hao
× Lyu, Hao× Hisatomi, Takashi× Goto, Yosuke× Yoshida, Masaaki× Higashi, Tomohiro× Katayama, Masao× Takata, Tsuyoshi× Minegishi, Tsutomu× Nishiyama, Hiroshi× Yamada, Taro× Sakata, Yoshihisa× Asakura, Kiyotaka× Domen, Kazunari |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Hisatomi, Takashi | |||||
URL | https://soar-rd.shinshu-u.ac.jp/profile/ja.ghSpPhyV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Takata, Tsuyoshi | |||||
URL | https://soar-rd.shinshu-u.ac.jp/profile/ja.ZUAFuUyC.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Domen, Kazunari | |||||
URL | https://soar-rd.shinshu-u.ac.jp/profile/ja.yafCOeLV.html | |||||
出版者 | ||||||
出版者 | ROYAL SOC CHEMISTRY | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | CHEMICAL SCIENCE.10(11):3196-3201(2019) | |||||
書誌情報 |
CHEMICAL SCIENCE 巻 10, 号 11, p. 3196-3201, 発行日 2019-01-24 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Photocatalytic water splitting is a viable approach to the large-scale production of renewable solar hydrogen. The apparent quantum yield for this reaction has been improved, but the lifespan of photocatalysts functioning under sunlight at ambient pressure have rarely been examined, despite the critical importance of this factor in practical applications. Herein, we show that Al-doped SrTiO3 (SrTiO3: Al) loaded with a RhCrOx (rhodium chromium oxide) cocatalyst splits water with an apparent quantum yield greater than 50% at 365 nm. Moreover, following the photodeposition of CoOOH and TiO2, this material maintains 80% of its initial activity and a solar-to-hydrogen energy conversion efficiency greater than or equal to 0.3% over a span of 1300 h under constant illumination by simulated sunlight at ambient pressure. This result is attributed to reduced dissolution of Cr in the cocatalyst following the oxidative photodeposition of CoOOH. The photodeposition of TiO2 further improves the durability of this photocatalyst. This work demonstrates a concept that could allow the design of longterm, large-scale photocatalyst systems for practical sunlight-driven water splitting. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | EISSN | |||||
収録物識別子 | 2041-6520 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12555653 | |||||
PubMed | ||||||
関連識別子 | ||||||
識別子タイプ | PMID | |||||
関連識別子 | https://www.ncbi.nlm.nih.gov/pubmed/30996901 | |||||
関連名称 | ||||||
関連名称 | 30996901 | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/c8sc05757e | |||||
関連名称 | ||||||
関連名称 | 10.1039/c8sc05757e | |||||
権利 | ||||||
権利情報 | This journal is ©The Royal Society of Chemistry 2019. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000461228400001 |