{"_buckets": {"deposit": "f7134c2e-dcfb-440f-9070-c32ffb05aa19"}, "_deposit": {"id": "10234", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "10234"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00010234", "sets": ["1016:1017"]}, "author_link": ["32287", "32288", "32289"], "item_1628147817048": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-10-31", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20-21", "bibliographicPageEnd": "1371", "bibliographicPageStart": "1367", "bibliographicVolumeNumber": "25", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON-ASYMMETRY"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The syntheses of (+)- and (\u2212)-akolactone B and (+)-ancepsenolide were accomplished using a Pd-catalyzed carbonylation. As to the absolute configuration of akolactone B, making a comparison of the specific rotation of both enantiomers of synthetic akolactone B and the natural compound suggests that the absolute configuration at the 4-position of akolactone B is (R).", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON-ASYMMETRY. 25(20-21):1367-1371 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Makabe, Hidefumi", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jFSaPUkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000344825500003"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetasy.2014.08.008"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.tetasy.2014.08.008", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright \u00a9 2014 Elsevier Ltd. All rights reserved. /NOTICE: this is the author\u0027s version of a work that was accepted for publication in TETRAHEDRON-ASYMMETRY. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. 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As to the absolute configuration of akolactone B, making a comparison of the specific rotation of both enantiomers of synthetic akolactone B and the natural compound suggests that the absolute configuration at the 4-position of akolactone B is (R). (C) 2014 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hikosaka,  Gen", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "32287", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hattori,  Yasunao", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "32288", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Makabe,  Hidefumi", "creatorNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "32289", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Synthesis_of_both_enantiomer.pdf", "filesize": [{"value": "422.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 422700.0, "url": {"label": "Synthesis_of_both_enantiomer.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/10234/files/Synthesis_of_both_enantiomer.pdf"}, "version_id": "4acdbe1e-90a1-418b-abdc-3cd30102e1ca"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of both enantiomers of akolactone B and (+)-ancepsenolide", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of both enantiomers of akolactone B and (+)-ancepsenolide", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1016/1017"], "permalink_uri": "http://hdl.handle.net/10091/18103", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2015-02-17"}, "publish_date": "2015-02-17", "publish_status": "0", "recid": "10234", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of both enantiomers of akolactone B and (+)-ancepsenolide"], "weko_shared_id": -1}