{"_buckets": {"deposit": "c2d37457-bee0-431f-960f-59f43113a08f"}, "_deposit": {"id": "10249", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "10249"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00010249"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-09-30", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "39", "bibliographicPageEnd": "8352", "bibliographicPageStart": "8349", "bibliographicVolumeNumber": "69", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The aminopalladation of amino allylic alcohol using Cl2Pd(MeCN)(2) in CH2Cl2 gave the 2,6-disubstituted piperidine with excellent diastereoselectivity. This compound was successfully converted into (+)-azimine (1) using cross-metathesis and Shiina macrolactonization.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON. 69(39):8349-8352 (2013)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Makabe, Hidefumi", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jFSaPUkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000323796000002"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tet.2013.07.083"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.tet.2013.07.083", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2013 Elsevier Ltd."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4020", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4020", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861787", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Alkaloids; Piperidine; Natural product; Aminopalladation"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "STEREOSELECTIVE TOTAL SYNTHESES; INTRAMOLECULAR N-ALKYLATION; PIPERIDINE RING FORMATION; ACID; (-)-DESOXOPROSOPHYLLINE; ALKALOIDS; AZCARPINE; AZIMINE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The aminopalladation of amino allylic alcohol using Cl2Pd(MeCN)(2) in CH2Cl2 gave the 2,6-disubstituted piperidine with excellent diastereoselectivity. This compound was successfully converted into (+)-azimine (1) using cross-metathesis and Shiina macrolactonization. \u00a9 2013 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kurogome,  Yuji"}], "nameIdentifiers": [{"nameIdentifier": "32369", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kogiso,  Masaya"}], "nameIdentifiers": [{"nameIdentifier": "32370", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Looi,  Kok Kong"}], "nameIdentifiers": [{"nameIdentifier": "32371", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hattori,  Yasunao"}], "nameIdentifiers": [{"nameIdentifier": "32372", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Konno,  Hiroyuki"}], "nameIdentifiers": [{"nameIdentifier": "32373", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirota,  Mitsuru"}], "nameIdentifiers": [{"nameIdentifier": "32374", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Makabe,  Hidefumi"}], "nameIdentifiers": [{"nameIdentifier": "32375", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Total_synthesis_+-azimine_via_diastereoselective_aminopalladation.pdf", "filesize": [{"value": "558.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 558300.0, "url": {"label": "Total_synthesis_+-azimine_via_diastereoselective_aminopalladation.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/10249/files/Total_synthesis_+-azimine_via_diastereoselective_aminopalladation.pdf"}, "version_id": "271c9d44-8894-4d37-ba01-db9e6318112d"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Alkaloids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Piperidine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Natural product", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Aminopalladation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Total synthesis of (+)-azimine via diastereoselective aminopalladation", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Total synthesis of (+)-azimine via diastereoselective aminopalladation"}]}, "item_type_id": "6", "owner": "1", "path": ["1016/1017"], "permalink_uri": "http://hdl.handle.net/10091/17850", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2014-09-05"}, "publish_date": "2014-09-05", "publish_status": "0", "recid": "10249", "relation": {}, "relation_version_is_last": true, "title": ["Total synthesis of (+)-azimine via diastereoselective aminopalladation"], "weko_shared_id": null}