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Photoluminescence and photoconductivity of [(CnS)(8)Pc](2)M complex is very weak. Two photoluminescence bands were observed at around 400-650 and 720-800 nm in chloroform solution corresponding to the Soret and Q bands in the absorption spectra, respectively. However, the emission from Eu3+ ion (as well as Tb3+) was not found compared with other Eu complexes because the 5d levels of the Eu3+ ion lie higher than the triplet level of the ligand. The significant enhancement of the photoconductivity of [(C16S)(8)Pc](2)M after C-60 doping is reported. The photoconductivity is positive at the low electric field in the ohmic regime while it becomes negative at the high electric field upon photoexcitation with strongly absorbed light. The negative photoconductivity is attributed to space-charge effects. 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Optical properties of substituted phthalocyanine rare-earth metal complexes
http://hdl.handle.net/10091/17091
http://hdl.handle.net/10091/17091c77f3d56-7954-4a1b-a63f-3dac8d642100
名前 / ファイル | ライセンス | アクション |
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Optical_properties_substituted_phthalocyanine_rare-earth_meta_complexes.pdf (362.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-07-16 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Optical properties of substituted phthalocyanine rare-earth metal complexes | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1063/1.1316050 | |||||
関連名称 | 10.1063/1.1316050 | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Yoshino, K
× Yoshino, K× Lee, SB× Sonoda, T× Kawagishi, H× Hidayat, R× Nakayama, K× Ozaki, M× Ban, K× Nishizawa, K× Ohta, K× Shirai, H |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Ohta, K | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html | |||||
出版者 | ||||||
出版者 | AMER INST PHYSICS | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF APPLIED PHYSICS. 88(12):7137-7143 (2000) | |||||
書誌情報 |
JOURNAL OF APPLIED PHYSICS 巻 88, 号 12, p. 7137-7143, 発行日 2000-12-15 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Comparative study of optical properties of alkylthio-group-substituted phthalocyanine rare-earth metal sandwich complexes ([(CnS)(8)Pc](2)M,M=Eu,Lu,Tb) is presented. Photoluminescence and photoconductivity of [(CnS)(8)Pc](2)M complex is very weak. Two photoluminescence bands were observed at around 400-650 and 720-800 nm in chloroform solution corresponding to the Soret and Q bands in the absorption spectra, respectively. However, the emission from Eu3+ ion (as well as Tb3+) was not found compared with other Eu complexes because the 5d levels of the Eu3+ ion lie higher than the triplet level of the ligand. The significant enhancement of the photoconductivity of [(C16S)(8)Pc](2)M after C-60 doping is reported. The photoconductivity is positive at the low electric field in the ohmic regime while it becomes negative at the high electric field upon photoexcitation with strongly absorbed light. The negative photoconductivity is attributed to space-charge effects. The mechanism of photoluminescence and photoconductivity are discussed by taking the electronic energy schemes of phthalocyanine ligands and lanthanide ion and C-60 into consideration. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0021-8979 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00693547 | |||||
権利 | ||||||
権利情報 | Copyright© 2000 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in J. Appl. Phys. 88, 7137 (2000) and may be found at https://doi.org/10.1063/1.1316050 . | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000165543900027 |