{"_buckets": {"deposit": "2842ca6d-41ad-4577-8f23-6f5b91398cea"}, "_deposit": {"id": "11456", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11456"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011456", "sets": ["1163"]}, "author_link": ["35606", "35607", "35608", "35609", "35610", "35611"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "147", "bibliographicPageStart": "129", "bibliographicVolumeNumber": "466", "bibliographic_titles": [{"bibliographic_title": "MOLECULAR CRYSTALS AND LIQUID CRYSTALS"}]}]}, "item_6_description_19": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "This is a preprint of an article whose final and definitive form has been published in the MOLECULAR CRYSTALS AND LIQUID CRYSTALS © 2007 copyright Taylor \u0026 Francis; MOLECULAR CRYSTALS AND LIQUID CRYSTALS is available online at : http://www.informaworld.com/openurl?genre=article\u0026issn=1542-1406\u0026volume=466\u0026issue=1\u0026spage=129", "subitem_description_type": "Other"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "MOLECULAR CRYSTALS AND LIQUID CRYSTALS. 466(1): 129-147 (2007)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Ohta, K", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000247079600010"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "TAYLOR \u0026 FRANCIS LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1080/15421400601150304"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1080/15421400601150304", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1542-1406", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1542-1406", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11836169", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "crystal structure; Cu(II) complexes; metallomesogen; salen ligand with 4-substituted long alkoxy chains"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "TRANSITION-METAL-COMPLEXES; DISCOTIC LIQUID-CRYSTALS; OXOVANADIUM(IV) SALEN; COPPER(II) COMPLEXES; COLUMNAR; METALLOMESOGENS; DERIVATIVES; BEHAVIOR; PHASES; CORE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "A series of copper(II) salen complexes containing 4-substituted alkoxy chains of aromatic rings [Cu((4-CnH2n+1O)(2)salen)] (n = 3 (1), 4 (2), 6 (3), 8 (4), 10 (5), 12 (6), 14 (7), 16 (8), 18 (9), and 20 (10) and salen (N, N\u0027-ethylenebis(salicylideneiminato)) has been prepared, and single-crystal structures of 2 center dot H2O, 4, and 6 by an X-ray crystallographic analysis have been revealed. Complexes 4 and 6 form tetrahedrally distorted square planer structure with one-dimensional polymeric stacking by van der Waals interaction between the dramatically distorted salen moieties. Complexes 1-3 did not exhibit any mesophases, but complexes 4-10 with longer alkoxy chains of n = 8-20 showed the metallomesogen of a lamello-columnar (ColL) mesophase in the smectic layers with the nearly constant stacking distances, irrespective of the variation of the alkoxy chain lengths by the X-ray diffraction measurements, which show similar behaviors to the corresponding Ni(II) complexes of n = 14-20. The molecular assemblies and mesomorphic properties in relation to the single-crystal structures of 4 and 6 with the liquid crystals at higher temperature are discussed."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Abe,  Y"}], "nameIdentifiers": [{"nameIdentifier": "35606", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakazima,  N"}], "nameIdentifiers": [{"nameIdentifier": "35607", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanase,  T"}], "nameIdentifiers": [{"nameIdentifier": "35608", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katano,  S"}], "nameIdentifiers": [{"nameIdentifier": "35609", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mukai,  H"}], "nameIdentifiers": [{"nameIdentifier": "35610", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta,  K"}], "nameIdentifiers": [{"nameIdentifier": "35611", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Abe_MCLC.pdf", "filesize": [{"value": "2.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 2300000.0, "url": {"label": "Abe_MCLC.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11456/files/Abe_MCLC.pdf"}, "version_id": "019bdc07-1399-483b-b4d1-f57b916c4f7e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Syntheses, structures, and mesomorphism of a series of Cu(II) salen complexes with 4-substituted long alkoxy chains", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Syntheses, structures, and mesomorphism of a series of Cu(II) salen complexes with 4-substituted long alkoxy chains", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1163"], "permalink_uri": "http://hdl.handle.net/10091/276", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-09-07"}, "publish_date": "2007-09-07", "publish_status": "0", "recid": "11456", "relation": {}, "relation_version_is_last": true, "title": ["Syntheses, structures, and mesomorphism of a series of Cu(II) salen complexes with 4-substituted long alkoxy chains"], "weko_shared_id": -1}