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Their mesomorphic properties were compared alongside those of the previously reported 2,3,9,10,16,17,23,24-octakis(3,4-dialkoxyphenoxy) phthalocyaninato copper( II) complexes, referred to as [(CnO)(2)PhO](8)PcCu (2, n=10, 12, 14). The phase transition behaviour of these discotic compounds (1-3) varies considerably with the number of peripheral chains. The eight-chain- substituted (CnOPhO)(8)PcCu complexes (1) exhibited only one hexagonal columnar (Col(h)) mesophase and did not exhibit a cubic mesophase. Sixteen- chain- substituted [(CnO)(2)PhO](8)PcCu complexes (2) exhibited various columnar mesophases. In addition, the [(CnO)(2)PhO](8)PcCu (2) derivatives with n=12 and 14 exhibited a cubic mesophase with Pn3(-)m symmetry [Cub( Pn3(-)m)] over a very narrow temperature region (ca. 5-8 degrees C) at high temperatures. In contrast, the twenty-four-chain-substituted [(CnO)(3)PhO] 8PcCu (3) exhibited the Cub(Pn3(-)m) phase over a much wider temperature region (ca. 90 degrees C). Thus, it was revealed that these discotic compounds tend to exhibit a cubic mesophase on increasing the number and length of the peripheral chains. It should be emphasized that [(CnO)(2)PhO](8)PcCu (2, n=12, 14) and [(CnO)(3)PhO](8)PcCu ( 3, n=10, 12, 14) are the first discotic compounds exhibiting a thermotropic Cub(Pn3(-)m) phase."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ichihara, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "35612", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzukia, Ayumi"}], "nameIdentifiers": [{"nameIdentifier": "35613", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hatsusaka, Kazuaki"}], "nameIdentifiers": [{"nameIdentifier": "35614", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "35615", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf", "filesize": [{"value": "1.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1700000.0, "url": {"label": "LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11457/files/LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf"}, "version_id": "c24cf701-3a36-44ef-9d97-6b5e6f8a1ae3"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1163"], "permalink_uri": "http://hdl.handle.net/10091/267", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-08-07"}, "publish_date": "2007-08-07", "publish_status": "0", "recid": "11457", "relation": {}, "relation_version_is_last": true, "title": ["Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives"], "weko_shared_id": -1}
Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives
http://hdl.handle.net/10091/267
http://hdl.handle.net/10091/267f4762783-cb4d-4c7a-8f84-b34bcf938c2c
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-08-07 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Ichihara, Masahiro
× Ichihara, Masahiro× Suzukia, Ayumi× Hatsusaka, Kazuaki× Ohta, Kazuchika |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Ohta, Kazuchika | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html | |||||
出版者 | ||||||
出版者 | TAYLOR & FRANCIS LTD | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | LIQUID CRYSTALS. 34(5): 555-567 (2007) | |||||
書誌情報 |
Liquid crystals 巻 34, 号 5, p. 555-567, 発行日 2007-05 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | This is a preprint of an article whose final and definitive form has been published in the LIQUID CRYSTALS © 2007 copyright Taylor & Francis; LIQUID CRYSTALS is available online at: http://www.informaworld.com/openurl?genre=article&issn=0267-8292&volume=34&issue=5&spage=555 | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0267-8292 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10692755 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1080/02678290701284238 | |||||
関連名称 | 10.1080/02678290701284238 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000246811400003 |