{"_buckets": {"deposit": "2688ea79-a5c4-425f-8c43-14064f7f3686"}, "_deposit": {"id": "11457", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11457"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011457"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "567", "bibliographicPageStart": "555", "bibliographicVolumeNumber": "34", "bibliographic_titles": [{"bibliographic_title": "Liquid crystals"}]}]}, "item_6_description_19": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "This is a preprint of an article whose final and definitive form has been published in the LIQUID CRYSTALS \u00a9 2007 copyright Taylor \u0026 Francis; LIQUID CRYSTALS is available online at: http://www.informaworld.com/openurl?genre=article\u0026issn=0267-8292\u0026volume=34\u0026issue=5\u0026spage=555", "subitem_description_type": "Other"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8\uff1amime\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "LIQUID CRYSTALS. 34(5): 555-567 (2007)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Ohta, Kazuchika", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.yVLFjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000246811400003"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "TAYLOR \u0026 FRANCIS LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1080/02678290701284238"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1080/02678290701284238", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0267-8292", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0267-8292", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10692755", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "X-RAY-DIFFRACTION; PHASE-TRANSITIONS; COLUMNAR; MESOMORPHISM; SILVER(I); SYSTEMS; SERIES"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "In order to obtain discotic compounds exhibiting a cubic mesophase, we synthesised two new series of discotic compounds, 2,3,9,10,16,17,23,24- octakis( 4- alkoxyphenoxy) phthalocyaninato copper(II) complexes, referred to as ( CnOPhO)(8)PcCu (1, n=10, 12, 14), and 2,3,9,10,16,17,23,24-octakis(3,4,5-trialkoxyphenoxy)phthalocyaninato copper(II) complexes, referred to as [(CnO)(3)PhO](8)PcCu (3, n=10, 12, 14), which both contain octakis( phenoxy) phthalocyaninato copper(II) as the central core and eight or twenty- four long alkoxy chains in the periphery, respectively. Their mesomorphic properties were compared alongside those of the previously reported 2,3,9,10,16,17,23,24-octakis(3,4-dialkoxyphenoxy) phthalocyaninato copper( II) complexes, referred to as [(CnO)(2)PhO](8)PcCu (2, n=10, 12, 14). The phase transition behaviour of these discotic compounds (1-3) varies considerably with the number of peripheral chains. The eight-chain- substituted (CnOPhO)(8)PcCu complexes (1) exhibited only one hexagonal columnar (Col(h)) mesophase and did not exhibit a cubic mesophase. Sixteen- chain- substituted [(CnO)(2)PhO](8)PcCu complexes (2) exhibited various columnar mesophases. In addition, the [(CnO)(2)PhO](8)PcCu (2) derivatives with n=12 and 14 exhibited a cubic mesophase with Pn3(-)m symmetry [Cub( Pn3(-)m)] over a very narrow temperature region (ca. 5-8 degrees C) at high temperatures. In contrast, the twenty-four-chain-substituted [(CnO)(3)PhO] 8PcCu (3) exhibited the Cub(Pn3(-)m) phase over a much wider temperature region (ca. 90 degrees C). Thus, it was revealed that these discotic compounds tend to exhibit a cubic mesophase on increasing the number and length of the peripheral chains. It should be emphasized that [(CnO)(2)PhO](8)PcCu (2, n=12, 14) and [(CnO)(3)PhO](8)PcCu ( 3, n=10, 12, 14) are the first discotic compounds exhibiting a thermotropic Cub(Pn3(-)m) phase."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ichihara,  Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "35612", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzukia,  Ayumi"}], "nameIdentifiers": [{"nameIdentifier": "35613", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hatsusaka,  Kazuaki"}], "nameIdentifiers": [{"nameIdentifier": "35614", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta,  Kazuchika"}], "nameIdentifiers": [{"nameIdentifier": "35615", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf", "filesize": [{"value": "1.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1700000.0, "url": {"label": "LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11457/files/LIQUID CRYSTALS Vol34 No.5 Page555 567 Year2007.pdf"}, "version_id": "c24cf701-3a36-44ef-9d97-6b5e6f8a1ae3"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives"}]}, "item_type_id": "6", "owner": "1", "path": ["1162/1163"], "permalink_uri": "http://hdl.handle.net/10091/267", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2007-08-07"}, "publish_date": "2007-08-07", "publish_status": "0", "recid": "11457", "relation": {}, "relation_version_is_last": true, "title": ["Discotic liquid crystals of transition metal complexes 37: a thermotropic cubic mesophase having Pn3m symmetry exhibited by phthalocyanine-based derivatives"], "weko_shared_id": null}