{"_buckets": {"deposit": "0d83ebdc-b8a2-464c-9b77-258e718ee000"}, "_deposit": {"id": "11728", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11728"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011728", "sets": ["1169:1170"]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "636", "bibliographicPageStart": "623", "bibliographicVolumeNumber": "86", "bibliographic_titles": [{"bibliographic_title": "HETEROCYCLES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The title compound, 5,6-dihydrocyclohepta[b]indol-6-one (1), was synthesized from 2-chlorotropone (7) by a two-step sequence involving Pd-catalyzed amination with 2-bromoaniline (15) and subsequent Pd-catalyzed intramolecular Heck reaction. Besides its synthetic detail, some physical properties of 1, such as acidity, basicity and spectroscopic behavior, were also reported. Compound 1 was transformed into 6-(1H-pyrazol-1-yl)- and 6-(1H-1,2,3-triazol-1-yl)-5-azabenz[b]azulenes (13 and 14) as a potential ligand.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "HETEROCYCLES. 86(1):623-636 (2012)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Oda, Mitsunori", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000313766800045"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.3987/COM-12-S(N)60"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.3987/COM-12-S(N)60", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2013 The Japan Institute of Heterocyclic Chemistry"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00663739", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Indole; Tropone; Pd-Catalyzed Reaction; Pyrazole; Triazole"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "PALLADIUM-CATALYZED AMINATION; MARINE ALKALOID CAULERSIN; 2-ARYLAMINOTROPONES; 2-ANILINOTROPONES; BASICITIES"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The title compound, 5,6-dihydrocyclohepta[b]indol-6-one (1), was synthesized from 2-chlorotropone (7) by a two-step sequence involving Pd-catalyzed amination with 2-bromoaniline (15) and subsequent Pd-catalyzed intramolecular Heck reaction. Besides its synthetic detail, some physical properties of 1, such as acidity, basicity and spectroscopic behavior, were also reported. Compound 1 was transformed into 6-(1H-pyrazol-1-yl)- and 6-(1H-1,2,3-triazol-1-yl)-5-azabenz[b]azulenes (13 and 14) as a potential ligand."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Oda,  Mitsunori"}], "nameIdentifiers": [{"nameIdentifier": "35943", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito,  Kunihiro"}], "nameIdentifiers": [{"nameIdentifier": "35944", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takagi,  Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "35945", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujiwara,  Yurie"}], "nameIdentifiers": [{"nameIdentifier": "35946", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "H86_623.pdf", "filesize": [{"value": "995.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 995200.0, "url": {"label": "H86_623.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11728/files/H86_623.pdf"}, "version_id": "0fa56514-14a5-4154-a084-43ab849fffde"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Indole", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Tropone", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pd-Catalyzed Reaction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pyrazole", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Triazole", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Novel Efficient Synthesis and Properties of 5,6-Dihydrocyclohepta[b]indol-6-one, and Its Transformation to 6-Azolyl-5-azabenz[b]azulenes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Novel Efficient Synthesis and Properties of 5,6-Dihydrocyclohepta[b]indol-6-one, and Its Transformation to 6-Azolyl-5-azabenz[b]azulenes"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/17268", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2013-12-04"}, "publish_date": "2013-12-04", "publish_status": "0", "recid": "11728", "relation": {}, "relation_version_is_last": true, "title": ["Novel Efficient Synthesis and Properties of 5,6-Dihydrocyclohepta[b]indol-6-one, and Its Transformation to 6-Azolyl-5-azabenz[b]azulenes"], "weko_shared_id": null}