{"_buckets": {"deposit": "808c821a-578c-4a52-8757-08d9d03cc9cb"}, "_deposit": {"id": "11888", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11888"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011888", "sets": ["1170"]}, "author_link": ["36422", "36423", "36424", "36425", "36426", "36427", "36428", "36429"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2004", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "316", "bibliographicPageStart": "305", "bibliographicVolumeNumber": "64", "bibliographic_titles": [{"bibliographic_title": "Heterocycles"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "3-(3-methoxycarbonylazulen-1-yl)ethynyltriphenylphosphonium bromide was prepared from methyl 3-formylazulenecarboxylate. Its resonance structures were discussed on the basis of the H-1 and C-13 NMR spectroscopy. Furthermore, its reactivity with o-substituted aniline was examined. We found that 2-(1-methoxycarbonyl-azulen-3-yl)ethynyltriphenylphosphonium bromide reacted with o-substituted aniline except 2-aminophenol to give corresponding methyl 3-(benzazol-2-yl)azulene-1-carboxylate.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Heterocycles. Vol 64, Issue 1, 2004, pp.305-316.", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Shoji, T", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000227032200032"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Japan Institute of Heterocyclic Chemistry"}]}, "item_6_relation_46": {"attribute_name": "他の資源との関係：URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "http://www.heterocycles.jp/"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.heterocycles.jp/", "subitem_relation_type_select": "URI"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.3987/COM-04-S(P)27"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.3987/COM-04-S(P)27", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright© 2004 The Japan Institute of Heterocyclic Chemistry"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0385-5414", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00663739", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CROSS-COUPLING REACTION; REDOX BEHAVIOR; EASY ACCESS; AZULENES; DERIVATIVES; CARBON"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "3-(3-methoxycarbonylazulen-1-yl)ethynyltriphenylphosphonium bromide was prepared from methyl 3-formylazulenecarboxylate. Its resonance structures were discussed on the basis of the H-1 and C-13 NMR spectroscopy. Furthermore, its reactivity with o-substituted aniline was examined. We found that 2-(1-methoxycarbonyl-azulen-3-yl)ethynyltriphenylphosphonium bromide reacted with o-substituted aniline except 2-aminophenol to give corresponding methyl 3-(benzazol-2-yl)azulene-1-carboxylate."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Morita,  N"}], "nameIdentifiers": [{"nameIdentifier": "36422", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Moriyama,  S"}], "nameIdentifiers": [{"nameIdentifier": "36423", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shoji,  T"}], "nameIdentifiers": [{"nameIdentifier": "36424", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakashima,  M"}], "nameIdentifiers": [{"nameIdentifier": "36425", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Watanabe,  M"}], "nameIdentifiers": [{"nameIdentifier": "36426", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kikuchi,  S"}], "nameIdentifiers": [{"nameIdentifier": "36427", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito,  S"}], "nameIdentifiers": [{"nameIdentifier": "36428", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujimori,  K"}], "nameIdentifiers": [{"nameIdentifier": "36429", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Heterocycles 2004, 64, 305.pdf", "filesize": [{"value": "435.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 435800.0, "url": {"label": "Heterocycles 2004, 64, 305.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11888/files/Heterocycles 2004, 64, 305.pdf"}, "version_id": "639f45ad-6768-4110-8160-0f9cac4aeb2f"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of Azulen-3-ylheterocyclic Using 2-(1-Methoxycarbonylazulen-3-yl)ethynyltriphenylphosphonium Bromide", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of Azulen-3-ylheterocyclic Using 2-(1-Methoxycarbonylazulen-3-yl)ethynyltriphenylphosphonium Bromide", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/10067", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2010-05-18"}, "publish_date": "2010-05-18", "publish_status": "0", "recid": "11888", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of Azulen-3-ylheterocyclic Using 2-(1-Methoxycarbonylazulen-3-yl)ethynyltriphenylphosphonium Bromide"], "weko_shared_id": -1}