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The crystal structures of 4 and the synthetic intermediate 8 was determined by X-ray crystallographic analysis and the results reveal that (1) the benzene ring of 4 is distorted as a boat form with relatively small bending angles and (2) the azulene rings of 8 show large out-of-plane deformation along the short azulene molecular axis. (C) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kuroda,  S"}], "nameIdentifiers": [{"nameIdentifier": "36689", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Obata,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36690", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Thanh,  NC"}], "nameIdentifiers": [{"nameIdentifier": "36691", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyatake,  R"}], "nameIdentifiers": [{"nameIdentifier": "36692", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Horino,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36693", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oda,  M"}], "nameIdentifiers": [{"nameIdentifier": "36694", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "\u5c0f\u7530 \u6643\u898f\u3000TL552\uff3f08.pdf", "filesize": [{"value": "468.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 468900.0, "url": {"label": "\u5c0f\u7530 \u6643\u898f\u3000TL552\uff3f08.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11971/files/\u5c0f\u7530 \u6643\u898f\u3000TL552\uff3f08.pdf"}, "version_id": "ef90a26b-8def-4ed6-86b1-b83843ff0249"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis and structure of polyunsaturated [10]paracyclophane annulated by two azulene rings", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis and structure of polyunsaturated [10]paracyclophane annulated by two azulene rings"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/1060", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2008-05-30"}, "publish_date": "2008-05-30", "publish_status": "0", "recid": "11971", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis and structure of polyunsaturated [10]paracyclophane annulated by two azulene rings"], "weko_shared_id": null}