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H-1 NMR spectra of 4 and 5 exhibited an unequal shielding effect on the bridge hydrogens from the resulted it ring system, suggesting the existence of the significant homoconjugative transannular interaction on the nonadjacent carbons at the bridge and the discreteness of pi-conjugation of the annulene between two bonds at the C7-C8 and C11-C12 to localize the C8-11 dienyl and the remaining parts. The X-ray crystallographic structures of 4 and 5 show relatively short atomic distance between those bridge carbons, and clear bond alternation of the dienyl part and the bond convergence of the remaining part in these compounds, supporting the spectral properties. (C) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Zhang, YM"}], "nameIdentifiers": [{"nameIdentifier": "36695", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hisano, E"}], "nameIdentifiers": [{"nameIdentifier": "36696", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta, R"}], "nameIdentifiers": [{"nameIdentifier": "36697", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyatake, R"}], "nameIdentifiers": [{"nameIdentifier": "36698", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Horino, Y"}], "nameIdentifiers": [{"nameIdentifier": "36699", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oda, M"}], "nameIdentifiers": [{"nameIdentifier": "36700", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuroda, S"}], "nameIdentifiers": [{"nameIdentifier": "36701", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "小田 晃規 TL_888_2008.pdf", "filesize": [{"value": "122.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 122700.0, "url": {"label": "小田 晃規 TL_888_2008.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11972/files/小田 晃規 TL_888_2008.pdf"}, "version_id": "ebc3c4de-30c4-4d51-82f4-a84eb87a36c7"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/1059", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-05-30"}, "publish_date": "2008-05-30", "publish_status": "0", "recid": "11972", "relation": {}, "relation_version_is_last": true, "title": ["Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions"], "weko_shared_id": -1}
Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions
http://hdl.handle.net/10091/1059
http://hdl.handle.net/10091/10593fde4b8b-f4e8-4549-b44c-672d2ae059af
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-05-30 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Zhang, YM
× Zhang, YM× Hisano, E× Ohta, R× Miyatake, R× Horino, Y× Oda, M× Kuroda, S |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Oda, M | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html | |||||
出版者 | ||||||
出版者 | PERGAMON-ELSEVIER SCIENCE LTD | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | TETRAHEDRON LETTERS. 49(5): 888-892 (2008) | |||||
書誌情報 |
TETRAHEDRON LETTERS 巻 49, 号 5, p. 888-892, 発行日 2008-01-28 |
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資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0040-4039 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861801 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.tetlet.2007.11.161 | |||||
関連名称 | 10.1016/j.tetlet.2007.11.161 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
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