{"_buckets": {"deposit": "a3186950-c97a-4a4d-bfe8-30c2ea627dcd"}, "_deposit": {"id": "11972", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11972"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011972"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2008-01-28", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "892", "bibliographicPageStart": "888", "bibliographicVolumeNumber": "49", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON LETTERS"}]}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8\uff1amime\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON LETTERS. 49(5): 888-892 (2008)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Oda, M", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000253170200036"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetlet.2007.11.161"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.tetlet.2007.11.161", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "1,6-methano(10]annulene; tropylium cation; homoconjugation; transannular interactions; X-ray crystallographic analysis"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "BRIDGED ANNULENES; HOMOAROMATICITY; AROMATICITY; CRYSTAL; SYSTEM; IONS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The tropone-fused 1,6-methano[10]annulene 4 was synthesized from 3,4-bis(bromomethyl)- 1,6-methano[10]annulene and the protonation of 4 provided the hydroxytropylium ion-fused annulene 5. H-1 NMR spectra of 4 and 5 exhibited an unequal shielding effect on the bridge hydrogens from the resulted it ring system, suggesting the existence of the significant homoconjugative transannular interaction on the nonadjacent carbons at the bridge and the discreteness of pi-conjugation of the annulene between two bonds at the C7-C8 and C11-C12 to localize the C8-11 dienyl and the remaining parts. The X-ray crystallographic structures of 4 and 5 show relatively short atomic distance between those bridge carbons, and clear bond alternation of the dienyl part and the bond convergence of the remaining part in these compounds, supporting the spectral properties. (C) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Zhang,  YM"}], "nameIdentifiers": [{"nameIdentifier": "36695", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hisano,  E"}], "nameIdentifiers": [{"nameIdentifier": "36696", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohta,  R"}], "nameIdentifiers": [{"nameIdentifier": "36697", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyatake,  R"}], "nameIdentifiers": [{"nameIdentifier": "36698", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Horino,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36699", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oda,  M"}], "nameIdentifiers": [{"nameIdentifier": "36700", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuroda,  S"}], "nameIdentifiers": [{"nameIdentifier": "36701", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "\u5c0f\u7530 \u6643\u898f\u3000TL\uff3f888\uff3f2008.pdf", "filesize": [{"value": "122.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 122700.0, "url": {"label": "\u5c0f\u7530 \u6643\u898f\u3000TL\uff3f888\uff3f2008.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11972/files/\u5c0f\u7530 \u6643\u898f\u3000TL\uff3f888\uff3f2008.pdf"}, "version_id": "ebc3c4de-30c4-4d51-82f4-a84eb87a36c7"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/1059", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2008-05-30"}, "publish_date": "2008-05-30", "publish_status": "0", "recid": "11972", "relation": {}, "relation_version_is_last": true, "title": ["Discreteness of pi-conjugation of 1,6-methano[10]annulene by troponoid fusion at the 3,4-positions"], "weko_shared_id": null}