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The cyt c adsorbed on the modified gold electrode exhibited well-defined reversible electrochemical behavior in 10 mM phosphate buffer solution (PBS, pH 7.0). The surface concentration (F) of electroactive species, cyt c, on the binary SAMs was higher than that in single-component SAMs of T-COOH, and reached a maximum value of 9.2 x 10(-12) mol cm(-2) when the ratio of T-COOH to T-NH2 in adsorption solution was of 3:2, and the formal potential (E-0\u0027 = (E-pa + E-pc)/2) of cyt c was -0.032 V (vs. Ag vertical bar AgCl (3 M NaCl)) in a 10 mM PBS. The interaction between cyt c and the binary SAMs made the E-0\u0027 shift negatively when compared with that of cyt c in solution (+0.258 V vs. NHE, i.e., +0.058 V vs. Ag vertical bar AgCl (3 M NaCl)). The fractional coverage of bound cyt c was a 0.64 theoretical monolayer. 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  1. 040 理学部
  2. 0401 学術論文

Voltammetry of immobilized cytochrome c on novel binary self-assembled monolayers of thioctic acid and thioctic amide modified gold electrodes

http://hdl.handle.net/10091/175
f52282a0-d1a0-4a9d-9d71-1ce3f2bf81b9
名前 / ファイル ライセンス アクション
Immobilized_Cytochrome_c.pdf Immobilized_Cytochrome_c.pdf (486.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2007-04-20
タイトル
言語 en
タイトル Voltammetry of immobilized cytochrome c on novel binary self-assembled monolayers of thioctic acid and thioctic amide modified gold electrodes
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Ji, XP

× Ji, XP

WEKO 36792

Ji, XP

Search repository
Jin, BK

× Jin, BK

WEKO 36793

Jin, BK

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Jin, JY

× Jin, JY

WEKO 36794

Jin, JY

Search repository
Nakamura, T

× Nakamura, T

WEKO 36795

Nakamura, T

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信州大学研究者総覧へのリンク
氏名 Jin, JY
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jUThymkV.html
出版者
出版者 ELSEVIER SCIENCE SA
引用
内容記述タイプ Other
内容記述 JOURNAL OF ELECTROANALYTICAL CHEMISTRY. 590(2): 173-180 (2006)
書誌情報 JOURNAL OF ELECTROANALYTICAL CHEMISTRY

巻 590, 号 2, p. 173-180, 発行日 2006-05-15
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0022-0728
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10836527
他の資源との関係:URI
関連識別子
識別子タイプ URI
関連識別子 http://www.elsevier.com/wps/find/journaldescription.cws_home/504087/description#description
関連名称
関連名称 http://www.elsevier.com/wps/find/journaldescription.cws_home/504087/description#description
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.jelechem.2006.03.011
関連名称
関連名称 10.1016/j.jelechem.2006.03.011
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000238304400008
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