{"_buckets": {"deposit": "1534a966-0ac9-491c-9cb6-851102fda3b2"}, "_deposit": {"id": "12305", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12305"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012305"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-11", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "657", "bibliographicPageStart": "651", "bibliographicVolumeNumber": "160", "bibliographic_titles": [{"bibliographic_title": "APPLIED CATALYSIS B-ENVIRONMENTAL"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Zinc oxide and layered zinc hydroxides were deposited from an aqueous solution of zinc nitrate at 323\u2013358 K on a substrate plate with a very thin titanium dioxide film by a photocatalytic reaction. The amorphous or low crystalline zinc hydroxide aggregates were deposited at a low temperature. The zinc oxide crystals with about 1\u20132 \u03bcm-sized hexagonal columns and 10 nm-sized spheres were formed at 338\u2013358 K. Nitrate ions in the solution were reduced to nitrite ions, and water was transformed into hydroxide ions by a photocatalytic reaction on the titanium dioxide film. The pH value increased on the substrate surface with the titanium dioxide film, which caused the zinc hydroxide formation on the film. The zinc hydroxides were then dehydrated and transformed into zinc oxide. The average crystallite size of the zinc oxide decreased with an increase in the reaction temperature because the reaction rates of the formation and dehydration of the zinc hydroxides increased which resulted in an increase in the formation rate of the crystal zinc oxide nuclei.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "APPLIED CATALYSIS B-ENVIRONMENTAL. 160:651-657 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Nishikiori, Hiromasa", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html"}, {"subitem_link_text": "Teshima, Katsuya", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gpcFbpkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000340687900071"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.apcatb.2014.06.019"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.apcatb.2014.06.019", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright \u00a9 2014 Elsevier Ltd. All rights reserved.NOTICE: this is the author\u0027s version of a work that was accepted for publication in APPLIED CATALYSIS B-ENVIRONMENTAL. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in APPLIED CATALYSIS B-ENVIRONMENTAL, VOL169, (2014) 10.1016/j.apcatb.2014.06.019"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0926-3373", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0926-3373", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1082551X", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Zinc oxide; Layered zinc hydroxide; Photocatalytic reaction; Titanium dioxide"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "ZINC-OXIDE FILMS; LAYERED DOUBLE HYDROXIDES; AQUEOUS-SOLUTION; CATHODIC ELECTRODEPOSITION; EFFICIENT PHOTOCATALYSTS; VISIBLE-LIGHT; DEPOSITION; DEGRADATION; NITRATE; GROWTH"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Zinc oxide and layered zinc hydroxides were deposited from an aqueous solution of zinc nitrate at 323-358 K on a substrate plate with a very thin titanium dioxide film by a photocatalytic reaction. The amorphous or low crystalline zinc hydroxide aggregates were deposited at a low temperature. The zinc oxide crystals with about 1-2 mu m-sized hexagonal columns and 10 nm-sized spheres were formed at 338-358 K. Nitrate ions in the solution were reduced to nitrite ions, and water was transformed into hydroxide ions by a photocatalytic reaction on the titanium dioxide film. The pH value increased on the substrate surface with the titanium dioxide film, which caused the zinc hydroxide formation on the film. The zinc hydroxides were then dehydrated and transformed into zinc oxide. The average crystallite size of the zinc oxide decreased with an increase in the reaction temperature because the reaction rates of the formation and dehydration of the zinc hydroxides increased which resulted in an increase in the formation rate of the crystal zinc oxide nuclei. (C) 2014 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nishikiori,  Hiromasa"}], "nameIdentifiers": [{"nameIdentifier": "37354", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagaya,  Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "37355", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takikawa,  Takumi"}], "nameIdentifiers": [{"nameIdentifier": "37356", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kikuchi,  Ayaka"}], "nameIdentifiers": [{"nameIdentifier": "37357", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamakami,  Tomohiko"}], "nameIdentifiers": [{"nameIdentifier": "37358", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wagata,  Hajime"}], "nameIdentifiers": [{"nameIdentifier": "37359", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Teshima,  Katsuya"}], "nameIdentifiers": [{"nameIdentifier": "37360", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujii,  Tsuneo"}], "nameIdentifiers": [{"nameIdentifier": "37361", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Formation_of_ZnO_thin_films.pdf", "filesize": [{"value": "2.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2200000.0, "url": {"label": "Formation_of_ZnO_thin_films.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12305/files/Formation_of_ZnO_thin_films.pdf"}, "version_id": "1eb67984-ce16-4b56-bdbf-eb50a4e04c41"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Zinc oxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Layered zinc hydroxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Photocatalytic reaction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Titanium dioxide", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Formation of ZnO thin films by photocatalytic reaction", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Formation of ZnO thin films by photocatalytic reaction"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/18117", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2015-03-05"}, "publish_date": "2015-03-05", "publish_status": "0", "recid": "12305", "relation": {}, "relation_version_is_last": true, "title": ["Formation of ZnO thin films by photocatalytic reaction"], "weko_shared_id": 3}