{"_buckets": {"deposit": "9d999610-6bb9-4c47-bc44-78d86751d58b"}, "_deposit": {"id": "12309", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12309"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012309", "sets": ["1222"]}, "author_link": ["37373", "37374", "37375"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-10-20", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "262", "bibliographicPageStart": "258", "bibliographicVolumeNumber": "614", "bibliographic_titles": [{"bibliographic_title": "CHEMICAL PHYSICS LETTERS"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2double bond; length as m-dashCdouble bond; length as m-dashO and a cyclopropanone⋯HCl complex. The cyclopropanone⋯HCl complex was further decomposed into CH2double bond; length as m-dashCH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "CHEMICAL PHYSICS LETTERS. 614:258-262 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Tanaka, Nobuaki", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gpDFyhne.html"}, {"subitem_link_text": "Nishikiori, Hiromasa", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000344429200049"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.cplett.2014.09.053"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.cplett.2014.09.053", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright © 2014 Elsevier B.V. All rights reserved.\u003cbr/\u003eNOTICE: this is the author\u0027s version of a work that was accepted for publication in CHEMICAL PHYSICS LETTERS. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in CHEMICAL PHYSICS LETTERS, VOL:614 (2014), DOI :10.1016/j.cplett.2014.09.053"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0009-2614", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0009-2614", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00602122", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "MATRIX-ISOLATION; CYCLOPROPANONE; CONFORMATION; RADICALS; ACETONES; CHLORIDE; DENSITY; ENERGY; CL"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2=C=O and a cyclopropanone center dot center dot center dot HCl complex. The cyclopropanone center dot center dot center dot HCl complex was further decomposed into CH2=CH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane. (C) 2014 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tanaka,  Nobuaki"}], "nameIdentifiers": [{"nameIdentifier": "37373", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Urashima,  Yoshitaka"}], "nameIdentifiers": [{"nameIdentifier": "37374", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishikiori,  Hiromasa"}], "nameIdentifiers": [{"nameIdentifier": "37375", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Photoinduced_reactions_of_chloroacetone.pdf", "filesize": [{"value": "577.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 577200.0, "url": {"label": "Photoinduced_reactions_of_chloroacetone.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12309/files/Photoinduced_reactions_of_chloroacetone.pdf"}, "version_id": "2a13b5b6-c8a7-4833-a155-41975309a2e1"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/18112", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2015-02-27"}, "publish_date": "2015-02-27", "publish_status": "0", "recid": "12309", "relation": {}, "relation_version_is_last": true, "title": ["Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3"], "weko_shared_id": -1}