| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2015-02-27 |
| タイトル |
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タイトル |
Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3 |
| 言語 |
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|
言語 |
eng |
| DOI |
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関連識別子 |
https://doi.org/10.1016/j.cplett.2014.09.053 |
|
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関連名称 |
10.1016/j.cplett.2014.09.053 |
| 資源タイプ |
|
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資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| 著者 |
Tanaka, Nobuaki
Urashima, Yoshitaka
Nishikiori, Hiromasa
|
| 信州大学研究者総覧へのリンク |
|
|
氏名 |
Tanaka, Nobuaki |
|
URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.gpDFyhne.html |
| 信州大学研究者総覧へのリンク |
|
|
氏名 |
Nishikiori, Hiromasa |
|
URL |
http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html |
| 出版者 |
|
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出版者 |
ELSEVIER SCIENCE BV |
| 引用 |
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内容記述 |
CHEMICAL PHYSICS LETTERS. 614:258-262 (2014) |
| 書誌情報 |
CHEMICAL PHYSICS LETTERS
巻 614,
p. 258-262,
発行日 2014-10-20
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| 抄録 |
|
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内容記述 |
The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2double bond; length as m-dashCdouble bond; length as m-dashO and a cyclopropanone⋯HCl complex. The cyclopropanone⋯HCl complex was further decomposed into CH2double bond; length as m-dashCH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane. |
| 資源タイプ（コンテンツの種類） |
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| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0009-2614 |
| 書誌レコードID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA00602122 |
| 権利 |
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|
権利情報 |
Copyright © 2014 Elsevier B.V. All rights reserved.<br/>NOTICE: this is the author's version of a work that was accepted for publication in CHEMICAL PHYSICS LETTERS. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in CHEMICAL PHYSICS LETTERS, VOL:614 (2014), DOI :10.1016/j.cplett.2014.09.053 |
| 出版タイプ |
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| WoS |
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|
URL |
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000344429200049 |
Photoinduced_reactions_of_chloroacetone.pdf (577.2 kB)
