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  1. 060 工学部
  2. 0601 学術論文

Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3

http://hdl.handle.net/10091/18112
http://hdl.handle.net/10091/18112
6adf35bf-fee3-47e9-8eea-51e0bc8df233
名前 / ファイル ライセンス アクション
Photoinduced_reactions_of_chloroacetone.pdf Photoinduced_reactions_of_chloroacetone.pdf (577.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2015-02-27
タイトル
タイトル Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COCICH3
言語
言語 eng
DOI
関連識別子 https://doi.org/10.1016/j.cplett.2014.09.053
関連名称 10.1016/j.cplett.2014.09.053
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Tanaka, Nobuaki

× Tanaka, Nobuaki

Tanaka, Nobuaki

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Urashima, Yoshitaka

× Urashima, Yoshitaka

Urashima, Yoshitaka

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Nishikiori, Hiromasa

× Nishikiori, Hiromasa

Nishikiori, Hiromasa

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信州大学研究者総覧へのリンク
氏名 Tanaka, Nobuaki
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.gpDFyhne.html
信州大学研究者総覧へのリンク
氏名 Nishikiori, Hiromasa
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html
出版者
出版者 ELSEVIER SCIENCE BV
引用
内容記述 CHEMICAL PHYSICS LETTERS. 614:258-262 (2014)
書誌情報 CHEMICAL PHYSICS LETTERS

巻 614, p. 258-262, 発行日 2014-10-20
抄録
内容記述 The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2double bond; length as m-dashCdouble bond; length as m-dashO and a cyclopropanone⋯HCl complex. The cyclopropanone⋯HCl complex was further decomposed into CH2double bond; length as m-dashCH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane.
資源タイプ(コンテンツの種類)
ISSN
収録物識別子タイプ ISSN
収録物識別子 0009-2614
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00602122
権利
権利情報 Copyright © 2014 Elsevier B.V. All rights reserved.<br/>NOTICE: this is the author's version of a work that was accepted for publication in CHEMICAL PHYSICS LETTERS. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in CHEMICAL PHYSICS LETTERS, VOL:614 (2014), DOI :10.1016/j.cplett.2014.09.053
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
WoS
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000344429200049
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