{"_buckets": {"deposit": "cc8016a4-4960-4a62-adbc-f9e033d89cc8"}, "_deposit": {"id": "12322", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12322"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012322", "sets": ["1221:1222"]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "950", "bibliographicPageStart": "946", "bibliographicVolumeNumber": "21", "bibliographic_titles": [{"bibliographic_title": "ULTRASONICS SONOCHEMISTRY"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Spherical gold nanoparticles (AuNPs) were selectively synthesized through sonochemical reduction of tetrachloride gold(III) ions ([AuCl4](-)) in an aqueous solution of hydrogen tetrachloroaurate(III) tetrahydrate (HAuCl4.H2O) with the aid of hydrogen (H-2) gas in the absence of any additional capping agents. On the other hand, various shaped-AuNPs such as spherical nanoparticles, triangular and hexagonal plates were formed from sonochemical reduction of [AuCl4](-) in argon (Ar)-, nitrogen (N-2)- or oxygen (O-2)-purged aqueous [AuCl4](-) solutions. The selective fabrication of spherical AuNPs assisted by H-2 gas is most likely attributed to the generation of hydrogen radicals (H center dot) promoted by the reaction of H-2 introduced and hydrogen oxide radicals (center dot OH) produced by sonolysis of water.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "ULTRASONICS SONOCHEMISTRY. 21(3):946-950 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Sakai, Toshio", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000332133800007"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_47": {"attribute_name": "PubMed", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "24405710"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search\u0026DB=pubmed\u0026term=24405710", "subitem_relation_type_select": "PMID"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.ultsonch.2013.12.010"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.ultsonch.2013.12.010", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2013 Elsevier B.V."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1350-4177", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1350-4177", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11024447", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Gold nanoparticles; Ultrasonication; High-frequency ultrasound; Sonochemical reduction; Dissolved gas; Hydrogen gas"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "SHAPE-CONTROLLED SYNTHESIS; ATOMIC-FORCE MICROSCOPY; AQUEOUS-SOLUTION; METAL-SURFACE; SIZE; NANOCRYSTALS; ADSORPTION; NANORODS; NANOSTRUCTURES; IRRADIATION"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Spherical gold nanoparticles (AuNPs) were selectively synthesized through sonochemical reduction of tetrachloride gold(III) ions ([AuCl4](-)) in an aqueous solution of hydrogen tetrachloroaurate(III) tetrahydrate (HAuCl4.H2O) with the aid of hydrogen (H-2) gas in the absence of any additional capping agents. On the other hand, various shaped-AuNPs such as spherical nanoparticles, triangular and hexagonal plates were formed from sonochemical reduction of [AuCl4](-) in argon (Ar)-, nitrogen (N-2)- or oxygen (O-2)-purged aqueous [AuCl4](-) solutions. The selective fabrication of spherical AuNPs assisted by H-2 gas is most likely attributed to the generation of hydrogen radicals (H center dot) promoted by the reaction of H-2 introduced and hydrogen oxide radicals (center dot OH) produced by sonolysis of water. \u00a9 2013 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sakai,  Toshio"}], "nameIdentifiers": [{"nameIdentifier": "37445", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Enomoto,  Hiroto"}], "nameIdentifiers": [{"nameIdentifier": "37446", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai,  Hideki"}], "nameIdentifiers": [{"nameIdentifier": "37447", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe,  Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "37448", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Hydrogen-assisted_fabrication_spherical_gold.pdf", "filesize": [{"value": "544.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 544800.0, "url": {"label": "Hydrogen-assisted_fabrication_spherical_gold.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12322/files/Hydrogen-assisted_fabrication_spherical_gold.pdf"}, "version_id": "6353527e-ec1b-422b-860b-6a46a335a841"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Gold nanoparticles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Ultrasonication", "subitem_subject_scheme": "Other"}, {"subitem_subject": "High-frequency ultrasound", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Sonochemical reduction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Dissolved gas", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydrogen gas", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Hydrogen-assisted fabrication of spherical gold nanoparticles through sonochemical reduction of tetrachloride gold(III) ions in water", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Hydrogen-assisted fabrication of spherical gold nanoparticles through sonochemical reduction of tetrachloride gold(III) ions in water"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/17708", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2014-07-09"}, "publish_date": "2014-07-09", "publish_status": "0", "recid": "12322", "relation": {}, "relation_version_is_last": true, "title": ["Hydrogen-assisted fabrication of spherical gold nanoparticles through sonochemical reduction of tetrachloride gold(III) ions in water"], "weko_shared_id": null}