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  1. 060 工学部 (Faculty of Engineering)
  2. 0601 学術論文 (Journal Articles)

Dimerization of xanthene dyes in sol-gel titania films

http://hdl.handle.net/10091/17699
8e4fe227-f9b9-4cec-8313-4c6ae6ea7443
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Dimerization_xanthene_dyes_sol-gel_titania.pdf Dimerization_xanthene_dyes_sol-gel_titania.pdf (830.2 kB)
item type 学術雑誌論文 / Journal Article(1)
公開日 2014-07-09
タイトル
タイトル Dimerization of xanthene dyes in sol-gel titania films
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Nishikiori, Hiromasa

× Nishikiori, Hiromasa

WEKO 37475

Nishikiori, Hiromasa

Search repository
Setiawan, Rudi Agus

× Setiawan, Rudi Agus

WEKO 37476

Setiawan, Rudi Agus

Search repository
Kawamoto, Sayaka

× Kawamoto, Sayaka

WEKO 37477

Kawamoto, Sayaka

Search repository
Takagi, Shinya

× Takagi, Shinya

WEKO 37478

Takagi, Shinya

Search repository
Teshima, Katsuya

× Teshima, Katsuya

WEKO 37479

Teshima, Katsuya

Search repository
Fujii, Tsuneo

× Fujii, Tsuneo

WEKO 37480

Fujii, Tsuneo

Search repository
信州大学研究者総覧へのリンク
Nishikiori, Hiromasa
http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html
信州大学研究者総覧へのリンク
Teshima, Katsuya
http://soar-rd.shinshu-u.ac.jp/profile/ja.gpcFbpkh.html
出版者
出版者 ROYAL SOC CHEMISTRY
引用
内容記述タイプ Other
内容記述 CATALYSIS SCIENCE & TECHNOLOGY. 3(10):2786-2792 (2013)
書誌情報 CATALYSIS SCIENCE & TECHNOLOGY

巻 3, 号 10, p. 2786-2792, 発行日 2013
抄録
内容記述タイプ Abstract
内容記述 Dye-dispersing titania gel films were prepared by the sol-gel method using titanium alkoxide solutions containing xanthene dyes, i.e., fluorescein, eosin Y, rhodamine 110, and rhodamine 123. Dimerization of the xanthene dyes in the films, depending on their concentrations, and their photoinduced electron transfer processes to the titania gels were investigated using spectroscopic and photoelectric techniques. The dye having a higher dimerization constant in solution formed a higher amount of the dimer in the titania gel. There was only a slight difference between the photoelectric conversion efficiencies of the monomer and dimer. The titanium species were coordinated to the carboxylate of the dyes. The dimers as well as the monomers were encapsulated in the narrow spaces of the gel films and strongly interacted with the surrounding titania matrix in the dye-dispersing titania gel films. The dye having a more nucleophilic carboxylate oxygen could easily form the coordination complex with the titanium species. The dye-titania interaction played an important role in the electron injection from the dye to the titania conduction band.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 2044-4753
DOI
関連識別子
識別子タイプ DOI
関連識別子 http://dx.doi.org/10.1039/c3cy00467h
関連名称
関連名称 10.1039/c3cy00467h
権利
権利情報 Copyright© 2013 Royal Society of Chemistry. Catal. Sci. Technol., 2013,3, 2786-2792 http://dx.doi.org/10.1039/C3CY00467H - Reproduced by permission of The Royal Society of Chemistry
著者版フラグ
値 author
WoS
Web of Science
http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000324404000039
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