{"_buckets": {"deposit": "f09eb0cd-50df-4331-81e7-cb9082b1a3bc"}, "_deposit": {"id": "12349", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12349"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012349", "sets": ["1221:1222"]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2011-07-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "240", "bibliographicPageStart": "236", "bibliographicVolumeNumber": "222", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The isomerization and metal chelation of spironaphthoxazine (SNO) in ethanol solutions have been investigated by measuring the UV-vis absorption spectra as a function of time. The protonated species of merocyanine (MC), an isomer of SNO, was gradually formed in the solutions containing SNO and aluminum ions in the dark. The proton was provided by the reaction of the aluminum ions with a slight amount of water contained in the ethanol solvent. The protonated species was slowly transformed into the aluminum chelate complex of MC by ligand exchange of the ethanol-solvated aluminum for MC in the dark. UV irradiation promoted the isomerization and chelation without forming the protonated species. The spectroscopic analysis with various compositional ratios of SNO and aluminum ions revealed that one aluminum ion was coordinated to three bidentate MC ligands in the ethanol solution.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY. 222(1):236-240 (2011)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Nishikiori, Hiromasa", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000295241600033"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE SA"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.jphotochem.2011.06.003"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.jphotochem.2011.06.003", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2011 Elsevier B.V."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1010-6030", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1010-6030", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10684407", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Chelation; Spironaphthoxazine; Aluminum; Photochromism; Spectroscopy"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "GEL-XEROGEL TRANSITIONS; OPTICAL-DATA STORAGE; DEPENDENT PHOTOCHROMISM; MAGNETIC-RESONANCE; SILICON ALKOXIDE; ZINC IONS; CHELATION; SPIROOXAZINE; COMPLEXES; COMPOUND"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The isomerization and metal chelation of spironaphthoxazine (SNO) in ethanol solutions have been investigated by measuring the UV-vis absorption spectra as a function of time. The protonated species of merocyanine (MC), an isomer of SNO, was gradually formed in the solutions containing SNO and aluminum ions in the dark. The proton was provided by the reaction of the aluminum ions with a slight amount of water contained in the ethanol solvent. The protonated species was slowly transformed into the aluminum chelate complex of MC by ligand exchange of the ethanol-solvated aluminum for MC in the dark. UV irradiation promoted the isomerization and chelation without forming the protonated species. The spectroscopic analysis with various compositional ratios of SNO and aluminum ions revealed that one aluminum ion was coordinated to three bidentate MC ligands in the ethanol solution. (C) 2011 Elsevier By. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nishikiori,  Hiromasa"}], "nameIdentifiers": [{"nameIdentifier": "37548", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takamura,  Toshikazu"}], "nameIdentifiers": [{"nameIdentifier": "37549", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimamura,  Suguru"}], "nameIdentifiers": [{"nameIdentifier": "37550", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujii,  Tsuneo"}], "nameIdentifiers": [{"nameIdentifier": "37551", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Photochromic_behavior_spironaphthoxazine_metal_ion-containing.pdf", "filesize": [{"value": "213.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 213900.0, "url": {"label": "Photochromic_behavior_spironaphthoxazine_metal_ion-containing.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12349/files/Photochromic_behavior_spironaphthoxazine_metal_ion-containing.pdf"}, "version_id": "562aab15-3523-44ed-b642-94c39df2e21d"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Chelation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Spironaphthoxazine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Aluminum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Photochromism", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Spectroscopy", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photochromic behavior of spironaphthoxazine in metal ion-containing solutions", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Photochromic behavior of spironaphthoxazine in metal ion-containing solutions"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/17208", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2013-10-21"}, "publish_date": "2013-10-21", "publish_status": "0", "recid": "12349", "relation": {}, "relation_version_is_last": true, "title": ["Photochromic behavior of spironaphthoxazine in metal ion-containing solutions"], "weko_shared_id": null}