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During the photocatalytic degradation of trichloroethylene using the allophane-TiO(2) nanocomposite, emission of the intermediate product, phosgene, was drastically inhibited. Trichloroethylene was transformed into the intermediate products, phosgene and dichloroacetyl chloride, on the TiO(2) during the UV irradiation. These compounds are rapidly adsorbed on the allophane. The compounds then gradually degraded after diffusing to the TiO(2).", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "APPLIED CATALYSIS B-ENVIRONMENTAL. 102(3-4):470-474 (2011)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Nishikiori, Hiromasa", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000287946800015"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.apcatb.2010.12.028"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.apcatb.2010.12.028", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2010 Elsevier B.V."}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0926-3373", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0926-3373", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1082551X", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Allophane; Titanium dioxide; Photocatalysis; Trichloroethylene; Adsorption"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "PHOTOCATALYTIC DEGRADATION; GAS-PHASE; REACTION PATHWAYS; TIO2; OXIDATION; PHOTOOXIDATION; MORPHOLOGY; MECHANISM; PRODUCTS; SURFACE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "A highly adsorptive allophane-TiO(2) nanocomposite photocatalyst was prepared by dispersing nanopartides of the natural clay mineral allophane into a titanium alkoxide solution by the sol-gel method. During the photocatalytic degradation of trichloroethylene using the allophane-TiO(2) nanocomposite, emission of the intermediate product, phosgene, was drastically inhibited. Trichloroethylene was transformed into the intermediate products, phosgene and dichloroacetyl chloride, on the TiO(2) during the UV irradiation. These compounds are rapidly adsorbed on the allophane. The compounds then gradually degraded after diffusing to the TiO(2).(C) 2010 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nishikiori,  Hiromasa"}], "nameIdentifiers": [{"nameIdentifier": "37569", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Furukawa,  Masaru"}], "nameIdentifiers": [{"nameIdentifier": "37570", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujii,  Tsuneo"}], "nameIdentifiers": [{"nameIdentifier": "37571", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Degradation_trichloroethylene_using_highly_adsorptive.pdf", "filesize": [{"value": "431.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 431300.0, "url": {"label": "Degradation_trichloroethylene_using_highly_adsorptive.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12353/files/Degradation_trichloroethylene_using_highly_adsorptive.pdf"}, "version_id": "01f804b5-27d6-4cf9-9723-5ed0258b4d94"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Allophane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Titanium dioxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Photocatalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Trichloroethylene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Adsorption", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Degradation of trichloroethylene using highly adsorptive allophane-TiO(2) nanocomposite", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Degradation of trichloroethylene using highly adsorptive allophane-TiO(2) nanocomposite"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/17204", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2013-10-21"}, "publish_date": "2013-10-21", "publish_status": "0", "recid": "12353", "relation": {}, "relation_version_is_last": true, "title": ["Degradation of trichloroethylene using highly adsorptive allophane-TiO(2) nanocomposite"], "weko_shared_id": null}