{"_buckets": {"deposit": "5f5102ed-a7a5-46b1-95d3-e8b2868fe940"}, "_deposit": {"id": "12370", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12370"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012370", "sets": ["1222"]}, "author_link": ["37639", "37640", "37641", "37642"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-03", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "495", "bibliographicPageStart": "487", "bibliographicVolumeNumber": "248", "bibliographic_titles": [{"bibliographic_title": "JOURNAL OF HAZARDOUS MATERIALS"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We report here on the removal of alkylphenols (phenol, 4-n-propylphenol, 4-n-heptylphenol and 4-nonylphenol) dissolved in water using the composite particles of nanocrystalline titania and alkyltrimethylammonium bromide (CnH2n+1N(CH3)(3)Br, C(n)TAB; n = 12, 14, 16 and 18) (named as TiO2/C(n)TAB Nanoskeleton) as adsorbents and photocatalysts. In particular, the adsorption of alkylphenols onto TiO2/C(n)TAB Nanoskeleton in water was investigated in terms of hydrophobic interaction between alkylphenols and C(n)TAB, surface area, pore structure and crystal size of TiO2/C(n)TAB Nanoskeleton. We revealed that C(n)TAB incorporated in the TiO2/C(n)TAB Nanoskeleton promotes the adsorption of alkylphenols onto TiO2/C(n)TAB Nanoskeleton due to the hydrophobic interaction between alkylphenols and C(n)TAB. On the other hand, the surface area, pore structure and crystal size of TiO2/C(n)TAB Nanoskeleton did not affect the adsorption of allcylphenols onto TiO2/C(n)TAB Nanoskeleton. We also found that the alkylphenols dissolved in water were completely removed by the combination of adsorption and photocatalytic degradation by the TiO2/C(n)TAB Nanoskeleton under UV irradiation. These results prove that the TiO2/C(n)TAB Nanoskeleton acts as in tandem an adsorbent and a photocatalyst for removal of alkylphenols dissolved in water.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "JOURNAL OF HAZARDOUS MATERIALS. 248:487-495 (2013)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Sakai, Toshio", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}, {"subitem_link_text": "Okada, Tomohiko", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000317443800057"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_47": {"attribute_name": "PubMed", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "23419907"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search\u0026DB=pubmed\u0026term=23419907", "subitem_relation_type_select": "PMID"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.jhazmat.2013.01.043"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.jhazmat.2013.01.043", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright© 2013 Elsevier B.V."}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0304-3894", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0304-3894", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00699157", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Adsorption; Photocatalysis; Titania Nanoskeleton; Alkyltrimethylammonium bromide; Alkylphenols"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "MOLECULAR SELECTIVE ADSORPTION; CONFINED SURFACTANT PHASES; MESOPOROUS SILICA; FORMATION MECHANISM; ORGANIC-COMPOUNDS; CRYSTALLINE WALL; PARTICLES; PHENOL; MCM-41; SOLUBILIZATION"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "We report here on the removal of alkylphenols (phenol, 4-n-propylphenol, 4-n-heptylphenol and 4-nonylphenol) dissolved in water using the composite particles of nanocrystalline titania and alkyltrimethylammonium bromide (CnH2n+1N(CH3)(3)Br, C(n)TAB; n = 12, 14, 16 and 18) (named as TiO2/C(n)TAB Nanoskeleton) as adsorbents and photocatalysts. In particular, the adsorption of alkylphenols onto TiO2/C(n)TAB Nanoskeleton in water was investigated in terms of hydrophobic interaction between alkylphenols and C(n)TAB, surface area, pore structure and crystal size of TiO2/C(n)TAB Nanoskeleton. We revealed that C(n)TAB incorporated in the TiO2/C(n)TAB Nanoskeleton promotes the adsorption of alkylphenols onto TiO2/C(n)TAB Nanoskeleton due to the hydrophobic interaction between alkylphenols and C(n)TAB. On the other hand, the surface area, pore structure and crystal size of TiO2/C(n)TAB Nanoskeleton did not affect the adsorption of allcylphenols onto TiO2/C(n)TAB Nanoskeleton. We also found that the alkylphenols dissolved in water were completely removed by the combination of adsorption and photocatalytic degradation by the TiO2/C(n)TAB Nanoskeleton under UV irradiation. These results prove that the TiO2/C(n)TAB Nanoskeleton acts as in tandem an adsorbent and a photocatalyst for removal of alkylphenols dissolved in water. (C) 2013 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sakai,  Toshio"}], "nameIdentifiers": [{"nameIdentifier": "37639", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Da, Loves, Albar"}], "nameIdentifiers": [{"nameIdentifier": "37640", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada,  Tomohiko"}], "nameIdentifiers": [{"nameIdentifier": "37641", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mishima,  Shozi"}], "nameIdentifiers": [{"nameIdentifier": "37642", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Titania_C-n_TAB_Nanoskeleton_adsorbent_photocatalyst.pdf", "filesize": [{"value": "785.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 785000.0, "url": {"label": "Titania_C-n_TAB_Nanoskeleton_adsorbent_photocatalyst.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12370/files/Titania_C-n_TAB_Nanoskeleton_adsorbent_photocatalyst.pdf"}, "version_id": "c09b4940-0b52-415b-9903-80e7df422e03"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Adsorption", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Photocatalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Titania Nanoskeleton", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Alkyltrimethylammonium bromide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Alkylphenols", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Titania/C-n TAB Nanoskeleton as adsorbent and photocatalyst for removal of alkylphenols dissolved in water", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Titania/C-n TAB Nanoskeleton as adsorbent and photocatalyst for removal of alkylphenols dissolved in water", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/17156", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2013-09-18"}, "publish_date": "2013-09-18", "publish_status": "0", "recid": "12370", "relation": {}, "relation_version_is_last": true, "title": ["Titania/C-n TAB Nanoskeleton as adsorbent and photocatalyst for removal of alkylphenols dissolved in water"], "weko_shared_id": -1}