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A small additive amount of Eu element was very effective in preparing transparent mica glass ceramics. However, the excess addition led to the coarsening of phase separation in the glass phase and the separation of unidentified crystal phases and beta-eucryptite during heating of the parent glasses, which caused white opaque at lower heating temperatures. When mica crystals were separated. Eu ions entered the interlayers of mica crystals. The observed emission and excitation spectra showed that parts of Eu3+ ions which were added as Eu2O3 were reduced to Eu2+ ions during melting of the starting materials and heating the parent glasses in air and the energy transfer from Eu2+ to Eu3+ ions occurred. (C) 2010 Elsevier Ltd and Techna Group S.r.l. 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Preparation and luminescent properties of Eu-doped transparent mica glass-ceramics
http://hdl.handle.net/10091/10735
http://hdl.handle.net/10091/1073508edb8fe-e3ae-4e47-9846-167f87e16938
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-10-26 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Preparation and luminescent properties of Eu-doped transparent mica glass-ceramics | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Optical properties | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Glass | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Glass ceramics | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Silicate | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Taruta, Seiichi
× Taruta, Seiichi× Matsuki, Mutsumi× Nishikiori, Hiromasa× Yamakami, Tomohiko× Yamaguchi, Tomohiro× Kitajima, Kunio |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Taruta, Seiichi | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.OacaZVkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Nishikiori, Hiromasa | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Yamaguchi, Tomohiro | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnVbpkh.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCI LTD | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Ceramics International. 36(4):1303-1309 (2010) | |||||
書誌情報 |
CERAMICS INTERNATIONAL 巻 36, 号 4, p. 1303-1309, 発行日 2010-05 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Eu-doped transparent mica glass–ceramics were prepared, the influence of Eu-doping on the crystallization of the parent glasses was investigated and the luminescent properties of the parent glasses and the glass–ceramics were estimated. A small additive amount of Eu element was very effective in preparing transparent mica glass–ceramics. However, the excess addition led to the coarsening of phase separation in the glass phase and the separation of unidentified crystal phases and β-eucryptite during heating of the parent glasses, which caused white opaque at lower heating temperatures. When mica crystals were separated, Eu ions entered the interlayers of mica crystals. The observed emission and excitation spectra showed that parts of Eu³⁺ ions which were added as Eu₂O₃ were reduced to Eu²⁺ ions during melting of the starting materials and heating the parent glasses in air and the energy transfer from Eu²⁺ to Eu³⁺ ions occurred. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0272-8842 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10622625 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.ceramint.2009.12.020 | |||||
関連名称 | 10.1016/j.ceramint.2009.12.020 | |||||
権利 | ||||||
権利情報 | Copyright© 2010 Elsevier Ltd and Techna Group S.r.l. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000277745100019 |