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Ag NPs were grown on MWCNTs by laser-induced photoreduction of [Ag(NH3)(2)](+). The larger the initial [Ag(NH3)(2)](+) concentration, the bigger the average particle size. 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Ag NPs were grown on MWCNTs by laser-induced photoreduction of [Ag(NH3)(2)](+). The larger the initial [Ag(NH3)(2)](+) concentration, the bigger the average particle size. XRD investigations revealed the well-crystallized structure of the nanoparticles. (C) 2009 Elsevier Ltd. 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