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The spectra of optical constants for the crystallographic axes are derived by a Kramers-Kronig analysis. X-ray photoelectron spectroscopy (XPS) and the calculation of the electronic structure by using a discrete variational X alpha method are performed for CdMoO4. The calculation shows that the Cd 4d state is localized at the bottom region of the O 2p valence band, and the Cd 5s state has a significant contribution to the bottom of the conduction band, composed of the Mo 4d state. The XPS spectrum of CdMoO4 resembles that of CdWO4. Unlike the XPS spectrum, the optical spectra of CdMoO4 resemble those of scheelite CaMoO4 rather than CdWO4. An excitonic transition is observed as a weak shoulderlike structure in CdWO4, while it is not appreciable in CdMoO4. These experimental results are discussed in comparison with the theoretical calculation of electronic structures. The remarkable anisotropy of the optical spectra in CdMoO4 is explained by taking into account the presence of the Cd 5s state at the bottom of the conduction band. The dichroism of CdWO4 is discussed in terms of the chain structure of WO66- octahedra in wolframite crystals. The present study indicates that the Cd metal states play a crucial role in the optical properties near the fundamental absorption edge in both CdMoO4 and CdWO4."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Fujita,  M"}], "nameIdentifiers": [{"nameIdentifier": "38844", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itoh,  M"}], "nameIdentifiers": [{"nameIdentifier": "38845", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katagiri,  T"}], "nameIdentifiers": [{"nameIdentifier": "38846", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iri,  D"}], "nameIdentifiers": [{"nameIdentifier": "38847", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kitaura,  M"}], "nameIdentifiers": [{"nameIdentifier": "38848", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mikhailik,  VB"}], "nameIdentifiers": [{"nameIdentifier": "38849", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PRB77_155118.pdf", "filesize": [{"value": "297.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 297700.0, "url": {"label": "PRB77_155118.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12666/files/PRB77_155118.pdf"}, "version_id": "34f217ff-82e2-4b4c-86af-94808ebf8cc4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Optical anisotropy and electronic structures of CdMoO4 and CdWO4 crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Optical anisotropy and electronic structures of CdMoO4 and CdWO4 crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/1081", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-06-05"}, "publish_date": "2008-06-05", "publish_status": "0", "recid": "12666", "relation": {}, "relation_version_is_last": true, "title": ["Optical anisotropy and electronic structures of CdMoO4 and CdWO4 crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations"], "weko_shared_id": -1}
  1. 060 工学部
  2. 0601 学術論文

Optical anisotropy and electronic structures of CdMoO4 and CdWO4 crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations

http://hdl.handle.net/10091/1081
http://hdl.handle.net/10091/1081
2d411fe4-c3cc-45aa-9c7b-3e2a4a4128a2
名前 / ファイル ライセンス アクション
PRB77_155118.pdf PRB77_155118.pdf (297.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2008-06-05
タイトル
言語 en
タイトル Optical anisotropy and electronic structures of CdMoO4 and CdWO4 crystals: Polarized reflection measurements, x-ray photoelectron spectroscopy, and electronic structure calculations
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Fujita, M

× Fujita, M

WEKO 38844

Fujita, M

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Itoh, M

× Itoh, M

WEKO 38845

Itoh, M

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Katagiri, T

× Katagiri, T

WEKO 38846

Katagiri, T

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Iri, D

× Iri, D

WEKO 38847

Iri, D

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Kitaura, M

× Kitaura, M

WEKO 38848

Kitaura, M

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Mikhailik, VB

× Mikhailik, VB

WEKO 38849

Mikhailik, VB

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出版者
出版者 AMER PHYSICAL SOC
引用
内容記述タイプ Other
内容記述 PHYSICAL REVIEW B. 77(15): 155118 (2008)
書誌情報 PHYSICAL REVIEW B

巻 77, 号 15, 発行日 2008-04
内容記述
内容記述タイプ Other
内容記述 Copyright (c) 2008 American Physical Society
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1098-0121
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA11187113
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1103/PhysRevB.77.155118
関連名称 10.1103/PhysRevB.77.155118
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000255457400042
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