{"_buckets": {"deposit": "a26839f6-221f-4e5b-b45e-18ca4544e050"}, "_deposit": {"id": "12676", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12676"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012676"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-12-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "2149", "bibliographicPageStart": "2143", "bibliographicVolumeNumber": "42", "bibliographic_titles": [{"bibliographic_title": "Crystal engineering"}]}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8\uff1amime\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "MATERIALS RESEARCH BULLETIN. 42(12): 2143-2149 (2007)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Yamaguchi, T", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnVbpkh.html"}, {"subitem_link_text": "Taruta, S", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OacaZVkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000251270000023"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.materresbull.2007.01.009"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.materresbull.2007.01.009", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0025-5408", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0025-5408", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1126842X", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "layer compounds; microporous materials; intercalation reactions; electron microscopy; X-ray diffraction"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "POLYOL PROCESS; MOLECULAR-SIEVES; METAL-CLUSTERS; MONTMORILLONITE; SIZE; NANOPARTICLES; TEMPLATE; CATALYST"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Alumina-pillared fluorine micas form micropores in the interlayer region and exhibit cation exchangeability. Reduction of 3d transition metal cations (Cu2+ and Ni2+) in the interlayer regions of the cation exchanged alumina-pillared micas was attempted using ethylene glycol or diethylene glycol. The Cu2+-exchanged pillared mica led to the formation of a pillared mica composite containing interlayer zero-valence Cu-0 metal clusters along with Cu-0 metal fine particles on external surfaces of pillared mica flakes when refluxed in either ethylene glycol or diethylene glycol. Ni2+ cations in the interlayer region were also found to be reducible by refluxing in diethylene glycol. The zero-valence metal contained in the refluxed products occurs in three forms: M-0 clusters in the interlayer region, elongated fine particles sandwiched between silicate layers, and submicron spherical particles on external surfaces of mica crystals. The zero-valence metal/alumina-pillared mica composites thus obtained largely retained the micropore properties of the alumina-pillared micas. (c) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamaguchi,  T"}], "nameIdentifiers": [{"nameIdentifier": "38887", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Taruta,  S"}], "nameIdentifiers": [{"nameIdentifier": "38888", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamakami,  T"}], "nameIdentifiers": [{"nameIdentifier": "38889", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kitajima,  K"}], "nameIdentifiers": [{"nameIdentifier": "38890", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "mica_composites.pdf", "filesize": [{"value": "882.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 882500.0, "url": {"label": "mica_composites.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12676/files/mica_composites.pdf"}, "version_id": "df0cd4ab-7d00-456c-bf38-e51d07fac174"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Preparation of M-0 metal/alumina-pillared mica composites (M = Cu, Ni) by in situ reduction of interlayer M2+ ions of alumina-pillared fluorine micas", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Preparation of M-0 metal/alumina-pillared mica composites (M = Cu, Ni) by in situ reduction of interlayer M2+ ions of alumina-pillared fluorine micas"}]}, "item_type_id": "6", "owner": "1", "path": ["1221/1222"], "permalink_uri": "http://hdl.handle.net/10091/976", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2008-02-06"}, "publish_date": "2008-02-06", "publish_status": "0", "recid": "12676", "relation": {}, "relation_version_is_last": true, "title": ["Preparation of M-0 metal/alumina-pillared mica composites (M = Cu, Ni) by in situ reduction of interlayer M2+ ions of alumina-pillared fluorine micas"], "weko_shared_id": null}