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The novel ionic liquids [IL-B; N, N-diethyl-N-methyl(2-methoxyethyl)ammonium tetrafluoroborate (DEME-BF4) and IL- T; N, N- diethyl-N-methyl(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)! imide (DEME-TFSI)] are promising candidates for EDLC electrolytes in terms of high decomposition voltage (wide voltage window), nonflammability, easy handling, nonvolatility, and low production costs. Notably, the wide voltage window indicates that IL- B and IL-T are more advantageous in energy density than typical propylene carbonate-based electrolytes (i.e., TEA-BF4/ PC) and a conventional imidazolium type ionic liquid (i.e., 1-ethyl-3-methylimidazolium tetrafluoroborate, EMI-BF4). The effectiveness of IL-B and IL-T on the application to EDLC electrolytes has been confirmed by using KOH-activated mesophase pitch-based carbon fibers (MPCFs) as an electrode material. The combination of IL-T (IL-B) and KOH-activated MPCFs has provided 56 F/g (51 F/g) of high specific capacitance at maximum (1 mA/cm(2) discharge current density, 3.5 V charging voltage), which is equivalent to 224 F/g (204 F/g) in a conventional three-compartment measuring system. In addition, the specific capacitance of both ionic liquids has increased proportional to the increase in the applied voltage from 2.5 to 3.5 V, in contrast to the decline observed for TEA-BF4/ PC at 3.5 V. Furthermore, the mixture of the IL- B exhibiting high viscosity with propylene carbonate (1 M of IL-B in PC) has been found to provide an excellent capacitance behavior comparable to that observed for the pure IL-B. This indicates that the mixture has great potential for application to EDLC electrolytes, similar to pure IL-B and IL-T. (c) 2005 The Electrochemical Society."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kim, YJ"}], "nameIdentifiers": [{"nameIdentifier": "39124", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuzawa, Y"}], "nameIdentifiers": [{"nameIdentifier": "39125", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ozaki, S"}], "nameIdentifiers": [{"nameIdentifier": "39126", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Park, KC"}], "nameIdentifiers": [{"nameIdentifier": "39127", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, C"}], "nameIdentifiers": [{"nameIdentifier": "39128", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Endo, M"}], "nameIdentifiers": [{"nameIdentifier": "39129", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshida, H"}], "nameIdentifiers": [{"nameIdentifier": "39130", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masuda, G"}], "nameIdentifiers": [{"nameIdentifier": "39131", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sato, T"}], "nameIdentifiers": [{"nameIdentifier": "39132", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Dresselhaus, MS"}], "nameIdentifiers": [{"nameIdentifier": "39133", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "No_31.pdf", "filesize": [{"value": "198.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 198500.0, "url": {"label": "No_31.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12728/files/No_31.pdf"}, "version_id": "02f716d9-c7e7-428f-9b47-5865928aab84"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "High energy-density capacitor based on ammonium salt type ionic liquids and their mixing effect by propylene carbonate", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "High energy-density capacitor based on ammonium salt type ionic liquids and their mixing effect by propylene carbonate", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/113", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-02-19"}, "publish_date": "2007-02-19", "publish_status": "0", "recid": "12728", "relation": {}, "relation_version_is_last": true, "title": ["High energy-density capacitor based on ammonium salt type ionic liquids and their mixing effect by propylene carbonate"], "weko_shared_id": -1}
High energy-density capacitor based on ammonium salt type ionic liquids and their mixing effect by propylene carbonate
http://hdl.handle.net/10091/113
http://hdl.handle.net/10091/113b385d5c1-a616-4b4f-a8fc-c8fa3caede05
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-02-19 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | High energy-density capacitor based on ammonium salt type ionic liquids and their mixing effect by propylene carbonate | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Kim, YJ
× Kim, YJ× Matsuzawa, Y× Ozaki, S× Park, KC× Kim, C× Endo, M× Yoshida, H× Masuda, G× Sato, T× Dresselhaus, MS |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Endo, M | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.uUTmZhkh.html | |||||
出版者 | ||||||
出版者 | The Electrochemical Society | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Journal of the Electrochemical Society. 152(4):A710-A715 (2005) | |||||
書誌情報 |
Journal of the Electrochemical Society 巻 152, 号 4, p. A710-A715, 発行日 2005-03-01 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | © The Electrochemical Society, Inc. 2005. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproducted, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in JOURNAL OF THE ELECTROCHEMICAL SOCIETY 152 (4): A710-A715 2005. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0013-4651 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00697016 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1149/1.1869232 | |||||
関連名称 | 10.1149/1.1869232 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&KeyUT=000228521200009&DestApp=WOS |