{"_buckets": {"deposit": "de453b11-7a77-4d8a-a916-1e178e5ab7ec"}, "_deposit": {"id": "13317", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "13317"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00013317", "sets": ["1310"]}, "author_link": ["40358", "40359", "40360", "40361", "40362", "40363", "40364"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012-08-31", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "19", "bibliographicPageEnd": "4279", "bibliographicPageStart": "4272", "bibliographicVolumeNumber": "53", "bibliographic_titles": [{"bibliographic_title": "POLYMER"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The structural development of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fibers was analyzed by in situ X-ray diffraction and fiber temperature measurements. The PEN fiber was drawn continuously under three drawing stresses, where the neck-drawing point was fixed accurately by CO2 laser irradiation heating. The developed crystal structures of the drawn fibers depended on the drawing stresses, that is, only the alpha-crystal was obtained under a drawing stress of 148 MPa, an alpha-rich mixed crystal was obtained for 54 MPa, and a beta-rich mixed crystal was obtained under 23 MPa stress. Fiber containing over 70% beta-crystal was obtained in the third case. Orientation-induced crystallization rates (K) and crystallization induction times (t(0)) were estimated for the three drawing stresses: K = 2210 s(-1) and t(0) = 0.5 ms for 148 MPa, K = 940 s(-1) and t(0) = 1.0 ms for 54 MPa, and K= 655 s(-1) and t(0) = 4.0 ms for 23 MPa. In addition, the drawing stress acted as a definitive influence not only on the resulting crystal form but also on the chain conformation of the mesophase structure. The d-spacing of the (001\u0027) diffraction increased with drawing stress, and the longer (001\u0027) spacing generated the alpha-crystal while the comparatively shorter (001\u0027) spacing yielded the beta-crystal. The d-spacings of 1.27 and 1.23 nm for the drawing stresses of 148 and 23 MPa, respectively, were somewhat shorter than the c-axis lengths of the alpha- and beta-crystals of 1.32 and 1.27 nm, respectively.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "POLYMER. 53(19):4272-4279 (2012)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Kim, Kyoung-Hou", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OpLajFkV.html"}, {"subitem_link_text": "Ohkoshi, Yutaka", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jUkejekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000308576300030"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCI LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.polymer.2012.07.043"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.polymer.2012.07.043", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright© 2012 Elsevier Ltd."}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0032-3861", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0032-3861", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00776983", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Poly(ethylene 2,6-naphthalene dicarboxylate); Mesophase structure; CO2 laser-heated drawing"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "POLY(ETHYLENE-TEREPHTHALATE); CRYSTALLIZATION; NAPHTHALATE); PEN"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The structural development of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fibers was analyzed by in situ X-ray diffraction and fiber temperature measurements. The PEN fiber was drawn continuously under three drawing stresses, where the neck-drawing point was fixed accurately by CO2 laser irradiation heating. The developed crystal structures of the drawn fibers depended on the drawing stresses, that is, only the alpha-crystal was obtained under a drawing stress of 148 MPa, an alpha-rich mixed crystal was obtained for 54 MPa, and a beta-rich mixed crystal was obtained under 23 MPa stress. Fiber containing over 70% beta-crystal was obtained in the third case. Orientation-induced crystallization rates (K) and crystallization induction times (t(0)) were estimated for the three drawing stresses: K = 2210 s(-1) and t(0) = 0.5 ms for 148 MPa, K = 940 s(-1) and t(0) = 1.0 ms for 54 MPa, and K= 655 s(-1) and t(0) = 4.0 ms for 23 MPa. In addition, the drawing stress acted as a definitive influence not only on the resulting crystal form but also on the chain conformation of the mesophase structure. The d-spacing of the (001\u0027) diffraction increased with drawing stress, and the longer (001\u0027) spacing generated the alpha-crystal while the comparatively shorter (001\u0027) spacing yielded the beta-crystal. The d-spacings of 1.27 and 1.23 nm for the drawing stresses of 148 and 23 MPa, respectively, were somewhat shorter than the c-axis lengths of the alpha- and beta-crystals of 1.32 and 1.27 nm, respectively. © 2012 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kim,  Kyoung-Hou"}], "nameIdentifiers": [{"nameIdentifier": "40358", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Aida,  Ryo"}], "nameIdentifiers": [{"nameIdentifier": "40359", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kang,  Young-Ah"}], "nameIdentifiers": [{"nameIdentifier": "40360", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ikaga,  Toshifumi"}], "nameIdentifiers": [{"nameIdentifier": "40361", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohkoshi,  Yutaka"}], "nameIdentifiers": [{"nameIdentifier": "40362", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wataoka,  Isao"}], "nameIdentifiers": [{"nameIdentifier": "40363", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Urakawa,  Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "40364", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Effect_drawing_stress_mesophase_structure.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "Effect_drawing_stress_mesophase_structure.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/13317/files/Effect_drawing_stress_mesophase_structure.pdf"}, "version_id": "7c9b5609-8adc-4457-9489-514c01910145"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Poly(ethylene 2,6-naphthalene dicarboxylate)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Mesophase structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "CO2 laser-heated drawing", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Effect of drawing stress on mesophase structure formation of poly(ethylene 2,6-naphthalene dicarboxylate) fiber just after the neck-drawing point", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Effect of drawing stress on mesophase structure formation of poly(ethylene 2,6-naphthalene dicarboxylate) fiber just after the neck-drawing point", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/17800", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2014-08-06"}, "publish_date": "2014-08-06", "publish_status": "0", "recid": "13317", "relation": {}, "relation_version_is_last": true, "title": ["Effect of drawing stress on mesophase structure formation of poly(ethylene 2,6-naphthalene dicarboxylate) fiber just after the neck-drawing point"], "weko_shared_id": -1}